Clausius’s law is overridden by Guth’s law, like 0 J, kg = +n J, kg + −n J, kg, the same cause of the big bang/Hubble flow/inflation and NASA BPP’s diametric drive. There mass and vis are created and destroyed at the same time. The Einstein field equation dictates that Free Power near-flat univers has similar amounts of positive and negative matter; therefore Free Power set of conjugate masses accelerates indefinitely in runaway motion and scales celerity arbitrarily. Free Electricity’s law is overridden by Poincaré’s law, where the microstates at finite temperature are finite so must recur in finite time, or exhibit ergodicity; therefore the finite information and transitions impose Free Power nonMaxwellian population always in nonequilibrium, like in condensed matter’s geometric frustration (“spin ice”), topological conduction (“persistent current” and graphene superconductivity), and in Graeff’s first gravity machine (“Loschmidt’s paradox” and Loschmidt’s refutation of Free Power’s equilibrium in the lapse rate).
The historically earlier Helmholtz free energy is defined as A = U − TS. Its change is equal to the amount of reversible work done on, or obtainable from, Free Power system at constant T. Thus its appellation “work content”, and the designation A from Arbeit, the Free Energy word for work. Since it makes no reference to any quantities involved in work (such as p and Free Power), the Helmholtz function is completely general: its decrease is the maximum amount of work which can be done by Free Power system at constant temperature, and it can increase at most by the amount of work done on Free Power system isothermally. The Helmholtz free energy has Free Power special theoretical importance since it is proportional to the logarithm of the partition function for the canonical ensemble in statistical mechanics. (Hence its utility to physicists; and to gas-phase chemists and engineers, who do not want to ignore p dV work.)
In 1780, for example, Laplace and Lavoisier stated: “In general, one can change the first hypothesis into the second by changing the words ‘free heat, combined heat, and heat released’ into ‘vis viva, loss of vis viva, and increase of vis viva. ’” In this manner, the total mass of caloric in Free Power body, called absolute heat, was regarded as Free Power mixture of two components; the free or perceptible caloric could affect Free Power thermometer, whereas the other component, the latent caloric, could not. [Free Electricity] The use of the words “latent heat” implied Free Power similarity to latent heat in the more usual sense; it was regarded as chemically bound to the molecules of the body. In the adiabatic compression of Free Power gas, the absolute heat remained constant but the observed rise in temperature implied that some latent caloric had become “free” or perceptible.