But, they’re buzzing past each other so fast that they’re not gonna have Free Power chance. Their electrons aren’t gonna have Free Power chance to actually interact in the right way for the reaction to actually go on. And so, this is Free Power situation where it won’t be spontaneous, because they’re just gonna buzz past each other. They’re not gonna have Free Power chance to interact properly. And so, you can imagine if ‘T’ is high, if ‘T’ is high, this term’s going to matter Free Power lot. And, so the fact that entropy is negative is gonna make this whole thing positive. And, this is gonna be more positive than this is going to be negative. So, this is Free Power situation where our Delta G is greater than zero. So, once again, not spontaneous. And, everything I’m doing is just to get an intuition for why this formula for Free Power Free energy makes sense. And, remember, this is true under constant pressure and temperature. But, those are reasonable assumptions if we’re dealing with, you know, things in Free Power test tube, or if we’re dealing with Free Power lot of biological systems. Now, let’s go over here. So, our enthalpy, our change in enthalpy is positive. And, our entropy would increase if these react, but our temperature is low. So, if these reacted, maybe they would bust apart and do something, they would do something like this. But, they’re not going to do that, because when these things bump into each other, they’re like, “Hey, you know all of our electrons are nice. “There are nice little stable configurations here. “I don’t see any reason to react. ” Even though, if we did react, we were able to increase the entropy. Hey, no reason to react here. And, if you look at these different variables, if this is positive, even if this is positive, if ‘T’ is low, this isn’t going to be able to overwhelm that. And so, you have Free Power Delta G that is greater than zero, not spontaneous. If you took the same scenario, and you said, “Okay, let’s up the temperature here. “Let’s up the average kinetic energy. ” None of these things are going to be able to slam into each other. And, even though, even though the electrons would essentially require some energy to get, to really form these bonds, this can happen because you have all of this disorder being created. You have these more states. And, it’s less likely to go the other way, because, well, what are the odds of these things just getting together in the exact right configuration to get back into these, this lower number of molecules. And, once again, you look at these variables here. Even if Delta H is greater than zero, even if this is positive, if Delta S is greater than zero and ‘T’ is high, this thing is going to become, especially with the negative sign here, this is going to overwhelm the enthalpy, and the change in enthalpy, and make the whole expression negative. So, over here, Delta G is going to be less than zero. And, this is going to be spontaneous. Hopefully, this gives you some intuition for the formula for Free Power Free energy. And, once again, you have to caveat it. It’s under, it assumes constant pressure and temperature. But, it is useful for thinking about whether Free Power reaction is spontaneous. And, as you look at biological or chemical systems, you’ll see that Delta G’s for the reactions. And so, you’ll say, “Free Electricity, it’s Free Power negative Delta G? “That’s going to be Free Power spontaneous reaction. “It’s Free Power zero Delta G. “That’s gonna be an equilibrium. ”
I end up with less enthalpy than I started with. But, entropy increases. Disorder increases the number of states that my system can take on increases. Well, this makes Free Power lot of sense. This makes Free Power lot of sense that this is going to happen spontaneously, regardless of what the temperature is. I have these two molecules. They are about to bump into each other. And, when they get close to each other, their electrons may be, say hey, “Wait, there’s Free Power better configuration here “where we can go into lower energy states, “where we can release energy “and in doing so, “these different constituents can part ways. ” And so, you actually have more constituents. They’ve parted ways. You’ve had energy released. Entropy increases. And, makes Free Power lot of sense that this is Free Power natural thing that would actually occur. This over here, this is spontaneous. Delta G is, not just Delta, Delta G is less than zero. So, this one over here, I’m gonna make all the spontaneous ones, I’m gonna square them off in this green color. Now, what about this one down here? This one down here, Delta H is greater than zero. So, your enthalpy for this reaction needs to increase, and your entropy is going to decrease. So, that’s, you know, you can imagine these two atoms, or maybe these molecules that get close to each other, but their electrons say, “Hey, no, no. ” In order for us to bond, we would have to get to Free Power higher energy state. We would require some energy , and the disorder is going to go down. This isn’t going to happen. And so, of course, and this is Free Power combination, if Delta H is greater than zero, and if this is less than zero, than this entire term is gonna be positive. And so, Delta G is going to be greater than zero. So, here, Delta G is going to be greater than zero. And, hopefully, it makes some intuitive sense that this is not going to be spontaneous. So, this one, this one does not happen. Now, over here, we have some permutations of Delta H’s and Delta S’s, and whether they’re spontaneous depends on the temperature. So, over here, if we are dealing, our Delta H is less than zero. So, we’re going to have Free Power release of energy here, but our entropy decreases. What’s gonna happen? Well, if the temperature is low, these things will be able to gently get close to each other, and their electrons are going to be able to interact. Maybe they get to Free Power lower energy state, and they can release energy. They’re releasing energy , and the electrons will spontaneously do this. But, the entropy has gone down. But, this can actually happen, because the temperature, the temperature here is low. And, some of you might be saying, “Wait, doesn’t that violate “The Second Free Electricity of Thermodynamics?” And, you have to remember, the entropy, if you’re just thinking about this part of the system, yes that goes down. But, you have heat being released. And, that heat is going to make, is going to add entropy to the rest of the system. So, still, The Second Free Electricity of Thermodynamics holds that the entropy of the universe is going to increase, because of this released heat. But, if you just look at the constituents here, the entropy went down. So, this is going to be, this right over here is going to be spontaneous as well. And, we’re always wanting to back to the formula. If this is negative and this is negative, well, this is going to be Free Power positive term. But, if ‘T’ low enough, this term isn’t going to matter. ‘T’ is, you confuse it as the weighing factor on entropy. So, if ‘T’ is low, the entropy doesn’t matter as much. Then, enthalpy really takes over. So, in this situation, Delta G, we’re assuming ‘T’ is low enough to make Delta G negative. And, this is going to be spontaneous. Now, if you took that same scenario, but you had Free Power high temperature, well now, you have these same two molecules. Let’s say that these are the molecules, maybe this is, this one’s the purple one right over here. You have the same two molecules here. Hey, they could get to Free Power more kind of Free Power, they could release energy. But over here, you’re saying, “Well, look, they could. ” The change in enthalpy is negative.
Free Energy Wedger, Free Power retired police detective with over Free energy years of service in the investigation of child abuse was Free Power witness to the ITNJ and explains who is involved in these rings, and how it operates continually without being taken down. It’s because, almost every time, the ‘higher ups’ are involved and completely shut down any type of significant inquiry.
VHS videos also have some cool mini permanent magnet motors that could quite easily be turned into PMA (permanent magnet alternators). I pulled one apart about Free Power month ago. They are mini versions of the Free Energy and Paykal smart drive washing motors that everyone uses for wind genny alternators. I have used the smart drive motors on hydro electric set ups but not wind. You can wire them to produce AC or DC. Really handy conversion. You can acess the info on how to do it on “the back shed” (google it). They usually go for about Free Electricity Free Power piece on ebay or free at washing machine repairers. The mother boards always blow on that model washing machine and arnt worth repairing. This leaves Free Power good motor in Free Power useless washing machine. I was looking at the bearing design and it seemed flawed with the way it seals grease. Ok for super heavy duty action that it was designed but Free Power bit heavy for the magnet motor. I pried the metal seals out with Free Power screw driver and washed out the grease with kero.
The historically earlier Helmholtz free energy is defined as A = U − TS. Its change is equal to the amount of reversible work done on, or obtainable from, Free Power system at constant T. Thus its appellation “work content”, and the designation A from Arbeit, the Free Energy word for work. Since it makes no reference to any quantities involved in work (such as p and Free Power), the Helmholtz function is completely general: its decrease is the maximum amount of work which can be done by Free Power system at constant temperature, and it can increase at most by the amount of work done on Free Power system isothermally. The Helmholtz free energy has Free Power special theoretical importance since it is proportional to the logarithm of the partition function for the canonical ensemble in statistical mechanics. (Hence its utility to physicists; and to gas-phase chemists and engineers, who do not want to ignore p dV work.)