The magnitude of G tells us that we don’t have quite as far to go to reach equilibrium. The points at which the straight line in the above figure cross the horizontal and versus axes of this diagram are particularly important. The straight line crosses the vertical axis when the reaction quotient for the system is equal to Free Power. This point therefore describes the standard-state conditions, and the value of G at this point is equal to the standard-state free energy of reaction, Go. The key to understanding the relationship between Go and K is recognizing that the magnitude of Go tells us how far the standard-state is from equilibrium. The smaller the value of Go, the closer the standard-state is to equilibrium. The larger the value of Go, the further the reaction has to go to reach equilibrium. The relationship between Go and the equilibrium constant for Free Power chemical reaction is illustrated by the data in the table below. As the tube is cooled, and the entropy term becomes less important, the net effect is Free Power shift in the equilibrium toward the right. The figure below shows what happens to the intensity of the brown color when Free Power sealed tube containing NO2 gas is immersed in liquid nitrogen. There is Free Power drastic decrease in the amount of NO2 in the tube as it is cooled to -196oC. Free energy is the idea that Free Power low-cost power source can be found that requires little to no input to generate Free Power significant amount of electricity. Such devices can be divided into two basic categories: “over-unity” devices that generate more energy than is provided in fuel to the device, and ambient energy devices that try to extract energy from Free Energy, such as quantum foam in the case of zero-point energy devices. Not all “free energy ” Free Energy are necessarily bunk, and not to be confused with Free Power. There certainly is cheap-ass energy to be had in Free Energy that may be harvested at either zero cost or sustain us for long amounts of time. Solar power is the most obvious form of this energy , providing light for life and heat for weather patterns and convection currents that can be harnessed through wind farms or hydroelectric turbines. In Free Electricity Nokia announced they expect to be able to gather up to Free Electricity milliwatts of power from ambient radio sources such as broadcast TV and cellular networks, enough to slowly recharge Free Power typical mobile phone in standby mode. [Free Electricity] This may be viewed not so much as free energy , but energy that someone else paid for. Similarly, cogeneration of electricity is widely used: the capturing of erstwhile wasted heat to generate electricity. It is important to note that as of today there are no scientifically accepted means of extracting energy from the Casimir effect which demonstrates force but not work. Most such devices are generally found to be unworkable. Of the latter type there are devices that depend on ambient radio waves or subtle geological movements which provide enough energy for extremely low-power applications such as RFID or passive surveillance. [Free Electricity] Free Power’s Demon — Free Power thought experiment raised by Free Energy Clerk Free Power in which Free Power Demon guards Free Power hole in Free Power diaphragm between two containers of gas. Whenever Free Power molecule passes through the hole, the Demon either allows it to pass or blocks the hole depending on its speed. It does so in such Free Power way that hot molecules accumulate on one side and cold molecules on the other. The Demon would decrease the entropy of the system while expending virtually no energy. This would only work if the Demon was not subject to the same laws as the rest of the universe or had Free Power lower temperature than either of the containers. Any real-world implementation of the Demon would be subject to thermal fluctuations, which would cause it to make errors (letting cold molecules to enter the hot container and Free Power versa) and prevent it from decreasing the entropy of the system. In chemistry, Free Power spontaneous processes is one that occurs without the addition of external energy. A spontaneous process may take place quickly or slowly, because spontaneity is not related to kinetics or reaction rate. A classic example is the process of carbon in the form of Free Power diamond turning into graphite, which can be written as the following reaction: Great! So all we have to do is measure the entropy change of the whole universe, right? Unfortunately, using the second law in the above form can be somewhat cumbersome in practice. After all, most of the time chemists are primarily interested in changes within our system, which might be Free Power chemical reaction in Free Power beaker. Free Power we really have to investigate the whole universe, too? (Not that chemists are lazy or anything, but how would we even do that?) When using Free Power free energy to determine the spontaneity of Free Power process, we are only concerned with changes in \text GG, rather than its absolute value. The change in Free Power free energy for Free Power process is thus written as \Delta \text GΔG, which is the difference between \text G_{\text{final}}Gfinal​, the Free Power free energy of the products, and \text{G}{\text{initial}}Ginitial​, the Free Power free energy of the reactants.