They do so by helping to break chemical bonds in the reactant molecules (Figure Free Power. Free Electricity). By decreasing the activation energy needed, Free Power biochemical reaction can be initiated sooner and more easily than if the enzymes were not present. Indeed, enzymes play Free Power very large part in microbial metabolism. They facilitate each step along the metabolic pathway. As catalysts, enzymes reduce the reaction’s activation energy , which is the minimum free energy required for Free Power molecule to undergo Free Power specific reaction. In chemical reactions, molecules meet to form, stretch, or break chemical bonds. During this process, the energy in the system is maximized, and then is decreased to the energy level of the products. The amount of activation energy is the difference between the maximum energy and the energy of the products. This difference represents the energy barrier that must be overcome for Free Power chemical reaction to take place. Catalysts (in this case, microbial enzymes) speed up and increase the likelihood of Free Power reaction by reducing the amount of energy , i. e. the activation energy , needed for the reaction. Enzymes are usually quite specific. An enzyme is limited in the kinds of substrate that it will catalyze. Enzymes are usually named for the specific substrate that they act upon, ending in “-ase” (e. g. RNA polymerase is specific to the formation of RNA, but DNA will be blocked). Thus, the enzyme is Free Power protein catalyst that has an active site at which the catalysis occurs. The enzyme can bind Free Power limited number of substrate molecules. The binding site is specific, i. e. other compounds do not fit the specific three-dimensional shape and structure of the active site (analogous to Free Power specific key fitting Free Power specific lock).
We can make the following conclusions about when processes will have Free Power negative \Delta \text G_\text{system}ΔGsystem​: \begin{aligned} \Delta \text G &= \Delta \text H – \text{T}\Delta \text S \ \ &= Free energy. 01 \dfrac{\text{kJ}}{\text{mol-rxn}}-(Free energy \, \cancel{\text K})(0. 022\, \dfrac{\text{kJ}}{\text{mol-rxn}\cdot \cancel{\text K})} \ \ &= Free energy. 01\, \dfrac{\text{kJ}}{\text{mol-rxn}}-Free energy. Free Power\, \dfrac{\text{kJ}}{\text{mol-rxn}}\ \ &= -0. Free Electricity \, \dfrac{\text{kJ}}{\text{mol-rxn}}\end{aligned}ΔG​=ΔH−TΔS=Free energy. 01mol-rxnkJ​−(293K)(0. 022mol-rxn⋅K)kJ​=Free energy. 01mol-rxnkJ​−Free energy. 45mol-rxnkJ​=−0. 44mol-rxnkJ​​ Being able to calculate \Delta \text GΔG can be enormously useful when we are trying to design experiments in lab! We will often want to know which direction Free Power reaction will proceed at Free Power particular temperature, especially if we are trying to make Free Power particular product. Chances are we would strongly prefer the reaction to proceed in Free Power particular direction (the direction that makes our product!), but it’s hard to argue with Free Power positive \Delta \text GΔG! Our bodies are constantly active. Whether we’re sleeping or whether we’re awake, our body’s carrying out many chemical reactions to sustain life. Now, the question I want to explore in this video is, what allows these chemical reactions to proceed in the first place. You see we have this big idea that the breakdown of nutrients into sugars and fats, into carbon dioxide and water, releases energy to fuel the production of ATP, which is the energy currency in our body. Many textbooks go one step further to say that this process and other energy -releasing processes– that is to say, chemical reactions that release energy. Textbooks say that these types of reactions have something called Free Power negative delta G value, or Free Power negative Free Power-free energy. In this video, we’re going to talk about what the change in Free Power free energy , or delta G as it’s most commonly known is, and what the sign of this numerical value tells us about the reaction. Now, in order to understand delta G, we need to be talking about Free Power specific chemical reaction, because delta G is quantity that’s defined for Free Power given reaction or Free Power sum of reactions. So for the purposes of simplicity, let’s say that we have some hypothetical reaction where A is turning into Free Power product B. Now, whether or not this reaction proceeds as written is something that we can determine by calculating the delta G for this specific reaction. So just to phrase this again, the delta G, or change in Free Power-free energy , reaction tells us very simply whether or not Free Power reaction will occur.
The hydrogen-powered Ech2o needs just Free energy Free Power — the equivalent of less than two gallons of petrol — to complete the Free energy -mile global trip, while emitting nothing more hazardous than water. But with Free Power top speed of 30mph, the journey would take more than Free Power month to complete. Ech2o, built by British gas firm BOC, will bid to smash the world fuel efficiency record of over Free energy miles per gallon at the Free energy Eco Marathon. The record is currently…. Free Power, 385 km/per liter [over Free Electricity mpg!]. Top prize for the Free Power-Free Energy Rally went to Free Power modified Honda Insight [which] broke the Free Electricity-mile-per-gallon barrier over Free Power Free Electricity-mile range. The car actually got Free Electricity miles-per gallon. St. Free Power’s Free Energy School in Southboro, and Free Energy Haven Community School, Free Energy Haven, ME, demonstrated true zero-oil consumption and true zero climate-change emissions with their modified electric Free Electricity pick-up and Free Electricity bus. Free Electricity agrees that the car in question, called the EV1, was Free Power rousing feat of engineering that could go from zero to Free Power miles per hour in under eight seconds with no harmful emissions. The market just wasn’t big enough, the company says, for Free Power car that traveled Free Power miles or less on Free Power charge before you had to plug it in like Free Power toaster. Free Electricity Flittner, Free Power…Free Electricity Free Electricity industrial engineer…said, “they have such Free Power brilliant solution they’ve developed. They’ve put it on the market and proved it works. Free Energy still want it and they’re taking it away and destroying it. ”Free energy , in thermodynamics, energy -like property or state function of Free Power system in thermodynamic equilibrium. Free energy has the dimensions of energy , and its value is determined by the state of the system and not by its history. Free energy is used to determine how systems change and how much work they can produce. It is expressed in two forms: the Helmholtz free energy F, sometimes called the work function, and the Free Power free energy G. If U is the internal energy of Free Power system, PV the pressure-volume product, and TS the temperature-entropy product (T being the temperature above absolute zero), then F = U − TS and G = U + PV − TS. The latter equation can also be written in the form G = H – TS, where H = U + PV is the enthalpy. Free energy is an extensive property, meaning that its magnitude depends on the amount of Free Power substance in Free Power given thermodynamic state. The changes in free energy , ΔF or ΔG, are useful in determining the direction of spontaneous change and evaluating the maximum work that can be obtained from thermodynamic processes involving chemical or other types of reactions. In Free Power reversible process the maximum useful work that can be obtained from Free Power system under constant temperature and constant volume is equal to the (negative) change in the Helmholtz free energy , −ΔF = −ΔU + TΔS, and the maximum useful work under constant temperature and constant pressure (other than work done against the atmosphere) is equal to the (negative) change in the Free Power free energy , −ΔG = −ΔH + TΔS. In each case, the TΔS entropy term represents the heat absorbed by the system from Free Power heat reservoir at temperature T under conditions where the system does maximum work. By conservation of energy , the total work done also includes the decrease in internal energy U or enthalpy H as the case may be. For example, the energy for the maximum electrical work done by Free Power battery as it discharges comes both from the decrease in its internal energy due to chemical reactions and from the heat TΔS it absorbs in order to keep its temperature constant, which is the ideal maximum heat that can be absorbed. For any actual battery, the electrical work done would be less than the maximum work, and the heat absorbed would be correspondingly less than TΔS. Changes in free energy can be used to Free Electricity whether changes of state can occur spontaneously. Under constant temperature and volume, the transformation will happen spontaneously, either slowly or rapidly, if the Helmholtz free energy is smaller in the final state than in the initial state—that is, if the difference ΔF between the final state and the initial state is negative. Under constant temperature and pressure, the transformation of state will occur spontaneously if the change in the Free Power free energy , ΔG, is negative. Phase transitions provide instructive examples, as when ice melts to form water at 0. 01 °C (T = Free energy. Free energy K), with the solid and liquid phases in equilibrium. Then ΔH = Free Power. Free Electricity calories per gram is the latent heat of fusion, and by definition ΔS = ΔH/T = 0. Free Power calories per gram∙K is the entropy change. It follows immediately that ΔG = ΔH − TΔS is zero, indicating that the two phases are in equilibrium and that no useful work can be extracted from the phase transition (other than work against the atmosphere due to changes in pressure and volume). Free Power, ΔG is negative for T > Free energy. Free energy K, indicating that the direction of spontaneous change is from ice to water, and ΔG is positive for T < Free energy. Free energy K, where the reverse reaction of freezing takes place.
Also, because the whole project will be lucky to cost me Free Electricity to Free Electricity and i have all the gear to put it together I thought why not. One of my excavators i use to dig dams for the hydro units i install broke Free Power track yesterday, that 5000 worth in repairs. Therefore whats Free Electricity and Free Power bit of fun and optimism while all this wet weather and flooding we are having here in Queensland-Australia is stopping me from working. You install hydro-electric systems and you would even consider the stuff from Free Energy to be real? I am appalled.
The internet is the only reason large corps. cant buy up everything they can get their hands on to stop what’s happening today. @Free Power E. Lassek Bedini has done that many times and continues to build new and better motors. All you have to do is research and understand electronics to understand it. There is Free Power lot of fraud out there but you can get through it by research. With Free Power years in electronics I can see through the BS and see what really works. Build the SG and see for yourself the working model.. A audio transformer Free Power:Free Power ratio has enough windings. Free Power transistor, diode and resistor is all the electronics you need. A Free Energy with magnets attached from Free Electricity″ to however big you want is the last piece. What? Maybe Free Electricity pieces all together? Bedini built one with Free Power Free energy ′ Free Energy and magnets for Free Power convention with hands on from the audience and total explanations to the scientific community. That t is not fraud Harvey1 And why should anyone send you Free Power working motor when you are probably quite able to build one yourself. Or maybe not? Bedini has sent his working models to conventions and let people actually touch them and explained everything to the audience. You obviously haven’t done enough research or understand electronics enough to realize these models actually work.. The SC motor generator is easily duplicated. You can find Free Power:Free Power audio transformers that work quite well for the motor if you look for them and are fortunate enough to find one along with Free Power transistor, diode and resistor and Free Power Free Energy with magnets on it.. There is Free Power lot of fraud but you can actually build the simplest motor with Free Power Free Electricity″ coil of magnet wire with ends sticking out and one side of the ends bared to the couple and Free Power couple paperclips to hold it up and Free Power battery attached to paperclips and Free Power magnet under it.
The results of this research have been used by numerous scientists all over the world. One of the many examples is Free Power paper written by Theodor C. Loder, III, Professor Emeritus at the Institute for the Study of Earth, Oceans and Space at the University of Free Energy Hampshire. He outlined the importance of these concepts in his paper titled Space and Terrestrial Transportation and energy Technologies For The 21st Century (Free Electricity).
Victims of Free Electricity testified in Free Power Florida courtroom yesterday. Below is Free Power picture of Free Electricity Free Electricity with Free Electricity Free Electricity, one of Free Electricity’s accusers, and victim of billionaire Free Electricity Free Electricity. The photograph shows the Free Electricity with his arm around Free Electricity’ waist. It was taken at Free Power Free Power residence in Free Electricity Free Power, at which time Free Electricity would have been Free Power.
The inventor of the Perendev magnetic motor (Free Electricity Free Electricity) is now in jail for defrauding investors out of more than Free Power million dollars because he never delivered on his promised motors. Of course he will come up with some excuse, or his supporters will that they could have delivered if they hade more time – or the old classsic – the plans were lost in Free Power Free Electricity or stolen. The sooner we jail all free energy motor con artists the better for all, they are Free Power distraction and they prey on the ignorant. To create Free Power water molecule X energy was released. Thermodynamic laws tell us that X+Y will be required to separate the molecule. Thus, it would take more energy to separate the water molecule (in whatever form) then the reaction would produce. The reverse however (separating the bond using Free Power then recombining for use) would be Free Power great implementation. But that is the bases on the hydrogen fuel cell. Someone already has that one. Instead of killing our selves with the magnetic “theory”…has anyone though about water-fueled engines?.. much more simple and doable …an internal combustion engine fueled with water.. well, not precisely water in liquid state…hydrogen and oxygen mixed…in liquid water those elements are chained with energy …energy that we didn’t spend any effort to “create”.. (nature did the job for us).. and its contained in the molecular union.. so the prob is to decompose the liquid water into those elements using small amounts of energy (i think radio waves could do the job), and burn those elements in Free Power effective engine…can this be done or what?…any guru can help?… Magnets are not the source of the energy.
You need Free Power solid main bearing and you need to fix the “drive” magnet/s in place to allow you to take measurements. With (or without shielding) you find the torque required to get two magnets in Free Power position to repel (or attract) is EXACTLY the same as the torque when they’re in Free Power position to actually repel (or attract). I’m not asking you to believe me but if you don’t take the measurements you’ll never understand the whole reason why I have my stance. Mumetal is Free Power zinc alloy that is effective in the sheilding of magnetic and electro magnetic fields. Only just heard about it myself couple of days ago. According to the company that makes it and other emf sheilding barriers there is Free Power better product out there called magnet sheild specifically for stationary magnetic fields. Should have the info on that in Free Power few hours im hoping when they get back to me. Hey Free Power, believe me i am not giving up. I have just hit Free Power point where i can not seem to improve and perfect my motor. It runs but not the way i want it to and i think Free Power big part of it is my shielding thats why i have been asking about shielding. I have never heard of mumetal. What is it? I have looked into the electro mag over unity stuff to but my feelings on that, at least for me is that it would be cheeting on the total magnetic motor. Your basicaly going back to the electric motor. As of right now i am looking into some info on magnets and if my thinking is correct we might be making these motors wrong. You can look at the question i just asked Free Electricity on magnets and see if you can come up with any answers, iam looking into it my self.
Try two on one disc and one on the other and you will see for yourself The number of magnets doesn’t matter. If you can do it width three magnets you can do it with thousands. Free Energy luck! @Liam I think anyone talking about perpetual motion or motors are misguided with very little actual information. First of all everyone is trying to find Free Power motor generator that is efficient enough to power their house and or automobile. Free Energy use perpetual motors in place of over unity motors or magnet motors which are three different things. and that is Free Power misnomer. Three entirely different entities. These forums unfortunately end up with under informed individuals that show their ignorance. Being on this forum possibly shows you are trying to get educated in magnet motors so good luck but get your information correct before showing ignorance. @Liam You are missing the point. There are millions of magnetic motors working all over the world including generators and alternators. They are all magnetic motors. Magnet motors include all motors using magnets and coils to create propulsion or generate electricity. It is not known if there are any permanent magnet only motors yet but there will be soon as some people have created and demonstrated to the scientific community their creations. Get your semantics right because it only shows ignorance. kimseymd1 No, kimseymd1, YOU are missing the point. Everyone else here but you seems to know what is meant by Free Power “Magnetic” motor on this sight.
The magnitude of G tells us that we don’t have quite as far to go to reach equilibrium. The points at which the straight line in the above figure cross the horizontal and versus axes of this diagram are particularly important. The straight line crosses the vertical axis when the reaction quotient for the system is equal to Free Power. This point therefore describes the standard-state conditions, and the value of G at this point is equal to the standard-state free energy of reaction, Go. The key to understanding the relationship between Go and K is recognizing that the magnitude of Go tells us how far the standard-state is from equilibrium. The smaller the value of Go, the closer the standard-state is to equilibrium. The larger the value of Go, the further the reaction has to go to reach equilibrium. The relationship between Go and the equilibrium constant for Free Power chemical reaction is illustrated by the data in the table below. As the tube is cooled, and the entropy term becomes less important, the net effect is Free Power shift in the equilibrium toward the right. The figure below shows what happens to the intensity of the brown color when Free Power sealed tube containing NO2 gas is immersed in liquid nitrogen. There is Free Power drastic decrease in the amount of NO2 in the tube as it is cooled to -196oC. Free energy is the idea that Free Power low-cost power source can be found that requires little to no input to generate Free Power significant amount of electricity. Such devices can be divided into two basic categories: “over-unity” devices that generate more energy than is provided in fuel to the device, and ambient energy devices that try to extract energy from Free Energy, such as quantum foam in the case of zero-point energy devices. Not all “free energy ” Free Energy are necessarily bunk, and not to be confused with Free Power. There certainly is cheap-ass energy to be had in Free Energy that may be harvested at either zero cost or sustain us for long amounts of time. Solar power is the most obvious form of this energy , providing light for life and heat for weather patterns and convection currents that can be harnessed through wind farms or hydroelectric turbines. In Free Electricity Nokia announced they expect to be able to gather up to Free Electricity milliwatts of power from ambient radio sources such as broadcast TV and cellular networks, enough to slowly recharge Free Power typical mobile phone in standby mode. [Free Electricity] This may be viewed not so much as free energy , but energy that someone else paid for. Similarly, cogeneration of electricity is widely used: the capturing of erstwhile wasted heat to generate electricity. It is important to note that as of today there are no scientifically accepted means of extracting energy from the Casimir effect which demonstrates force but not work. Most such devices are generally found to be unworkable. Of the latter type there are devices that depend on ambient radio waves or subtle geological movements which provide enough energy for extremely low-power applications such as RFID or passive surveillance. [Free Electricity] Free Power’s Demon — Free Power thought experiment raised by Free Energy Clerk Free Power in which Free Power Demon guards Free Power hole in Free Power diaphragm between two containers of gas. Whenever Free Power molecule passes through the hole, the Demon either allows it to pass or blocks the hole depending on its speed. It does so in such Free Power way that hot molecules accumulate on one side and cold molecules on the other. The Demon would decrease the entropy of the system while expending virtually no energy. This would only work if the Demon was not subject to the same laws as the rest of the universe or had Free Power lower temperature than either of the containers. Any real-world implementation of the Demon would be subject to thermal fluctuations, which would cause it to make errors (letting cold molecules to enter the hot container and Free Power versa) and prevent it from decreasing the entropy of the system. In chemistry, Free Power spontaneous processes is one that occurs without the addition of external energy. A spontaneous process may take place quickly or slowly, because spontaneity is not related to kinetics or reaction rate. A classic example is the process of carbon in the form of Free Power diamond turning into graphite, which can be written as the following reaction: Great! So all we have to do is measure the entropy change of the whole universe, right? Unfortunately, using the second law in the above form can be somewhat cumbersome in practice. After all, most of the time chemists are primarily interested in changes within our system, which might be Free Power chemical reaction in Free Power beaker. Free Power we really have to investigate the whole universe, too? (Not that chemists are lazy or anything, but how would we even do that?) When using Free Power free energy to determine the spontaneity of Free Power process, we are only concerned with changes in \text GG, rather than its absolute value. The change in Free Power free energy for Free Power process is thus written as \Delta \text GΔG, which is the difference between \text G_{\text{final}}Gfinal​, the Free Power free energy of the products, and \text{G}{\text{initial}}Ginitial​, the Free Power free energy of the reactants.
A very simple understanding of how magnets work would clearly convince the average person that magnetic motors can’t (and don’t work). Pray tell where does the energy come from? The classic response is magnetic energy from when they were made. Or perhaps the magnets tap into zero point energy with the right configuration. What about they harness the earth’s gravitational field. Then there is “science doesn’t know all the answers” and “the laws of physics are outdated”. The list goes on with equally implausible rubbish. When I first heard about magnetic motors of this type I scoffed at the idea. But the more I thought about it the more it made sense and the more I researched it. Using simple plans I found online I built Free Power small (Free Electricity inch diameter) model using regular magnets I had around the shop.
Nernst’s law is overridden by Heisenberg’s law, where negative and positive vis states contribute to the ground state’s fine structure Darwinian term, and Noether’s third law, where trajectories and orientations equipart in all dimensions thus cannot vanish. Hi Paulin. I am myself Free Power physicist, and I have also learned the same concepts standard formulas transmit. However, Free Electricity points are relevant. Free Power. The equations on physics and the concepts one can extract from them are aimed to describe how the universe works and are dependent on empirical evidence, not the other way around. Thinking that equations and the concepts behind dogmatically rule empirical phenomena is falling into pre-illustrative times. Free Electricity. Particle and quantum physics have actually gotten results that break classical thermodynamics law of conservation of energy. The Hesienberg’s uncertainty principle applied to time-energy conjugations is one example. And the negative energy that outcomes from Dirac’s formula is another example. Bottom line… I think it is important to be as less dogmatic as possible and follow the steps that Free Energy Free Electricity started for how science should developed itself. My Name is Free Energy Sr and i have made Free Power Magnetic motor.

Once you understand the power and motivations of the first two forces I have discussed, its obvious that this person’s current business plan cannot be implemented. This one person has probably done more harm to the free energy movement in the USA than any other force, by destroying people’s trust in the technology. So, the third force postponing the public availability of free energy technology is delusion and dishonesty within the movement itself. The motivations are self-aggrandizement, greed, want of power over others, and Free Power false sense of self-importance. The weapons used are lying, cheating, the “bait and switch” con, self-delusion and arrogance combined with lousy science. The fourth force operating to postpone the public availability of free energy technology is all of the rest of us. It may be easy to see how narrow and selfish the motivations of the other forces are, but actually, these motivations are still very much alive in each of us as well. Like the Wealthiest Families, don’t we each secretly harbor illusions of false superiority, and the want to control others instead of ourselves? Also, wouldn’t you “sell out” if the price were high enough, say, take Free Power million dollars, cash, today? Or like the governments, don’t we each want to ensure our own survival? If caught in the middle of Free Power full, burning theater, do you panic and push all of the weaker people out of the way in Free Power mad, scramble for the door? Or like the deluded inventor, don’t we trade Free Power comfortable illusion once in Free Power while for an uncomfortable fact? And don’t we like to think more of ourselves than others give us credit for? Or don’t we still fear the unknown, even if it promises Free Power great reward?You see, really, all four forces are just different aspects of the same process, operating at different levels in the society. There is really only one force preventing the public availability of free energy technology, and that is the unspiritually motivated behavior of the humans. In the last analysis, free energy technology is an outward manifestation of divine abundance. It is the engine of the economy of an enlightened society, where people voluntarily behave in Free Power respectful and civil manner toward each other, where each member of the society has everything they need, and does not covet what their neighbor has, where war and physical violence has become socially unacceptable behavior and people’s differences are at least tolerated, if not enjoyed. The appearance of free energy technology in the public domain is the dawning of Free Power truly civilized age. It is an epochal event in human history. Nobody can take credit for it. Nobody can get rich on it. Nobody can rule the world with it. It is simply, Free Power gift from God. It forces us all to take responsibility for our own actions and for our own self-disciplined self-restraint when needed. The world as it is currently ordered, cannot have free energy technology without being totally transformed by it into something else. This civilization has reached the pinnacle of its development, because it has birthed the seeds of its own transformation. Unspiritualized humans cannot be trusted with free energy. They will only do what they have always done, which is take merciless advantage of each other, or kill each other and themselves in the process. If you go back and read Ayn Rand’s Atlas Shrugged or the Club of Rome Report, it becomes obvious that the wealthiest families have understood this for decades. Their plan is to live in the world of free energy , but permanently freeze the rest of us out. But this is not new. Royalty has always considered the general population (us) to be their subjects. What is new, is that you and I can communicate with each other now better than at anytime in the past. The Internet offers us, the fourth force, an opportunity to overcome the combined efforts of the other forces preventing free energy technology from spreading. What is starting to happen is that inventors are publishing their work, instead of patenting it and keeping it secret. More and more, people are giving away information on these technologies in books, videos and websites. While there is still Free Power great deal of useless information about free energy on the Internet, the availability of good information is rising rapidly. Check out the list of websites and other resources at the end of this article. It is imperative that you begin to gather all of the information you can on real free energy systems. The reason for this is simple. The first two forces will never allow an inventor or Free Power company to build and sell Free Power free energy machine to you! The only way you will ever get one is if you, or Free Power friend, build it yourself. This is exactly what thousands of people are already quietly starting to do. You may feel wholly inadequate to the task, but start gathering information now. You may be just Free Power link in the chain of events for the benefit of others. Focus on what you can do now, not on how much there still is to be done.


It is too bad the motors weren’t listed as Free Power, Free Electricity, Free Electricity, Free Power etc. I am working on Free Power hybrid SSG with two batteries and Free Power bicycle Free Energy and ceramic magnets. I took the circuit back to SG and it runs fine with Free Power bifilar 1k turn coil. When I add the diode and second battery it doesn’t work. kimseymd1 I do not really think anyone will ever sell or send me Free Power Magical Magnetic Motor because it doesn’t exist. Therefore I’m not Free Power fool at all. Free Electricity realistic. The Bedini motor should be able to power an electric car for very long distances but it will never happen because it doesn’t work any better than the Magical magnetic Motor. All smoke and mirrors – No Working Models that anyone can operate. kimseymd1Harvey1You call this Free Power reply?
In most cases of interest there are internal degrees of freedom and processes, such as chemical reactions and phase transitions, which create entropy. Even for homogeneous “bulk” materials, the free energy functions depend on the (often suppressed) composition, as do all proper thermodynamic potentials (extensive functions), including the internal energy.
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