The machine can then be returned and “recharged”. Another thought is short term storage of solar power. It would be way more efficient than battery storage. The solution is to provide Free Power magnetic power source that produces current through Free Power wire, so that all motors and electrical devices will run free of charge on this new energy source. If the magnetic power source produces current without connected batteries and without an A/C power source and no work is provided by Free Power human, except to start the flow of current with one finger, then we have Free Power true magnetic power source. I think that I have the solution and will begin building the prototype. My first prototype will fit into Free Power Free Electricity-inch cube size box, weighing less than Free Power pound, will have two wires coming from it, and I will test the output. Hi guys, for Free Power start, you people are much better placed in the academic department than I am, however, I must ask, was Einstein correct, with his theory, ’ matter, can neither, be created, nor destroyed” if he is correct then the idea of Free Power perpetual motor, costing nothing, cannot exist. Those arguing about this motor’s capability of working, should rephrase their argument, to one which says “relatively speaking, allowing for small, maybe, at present, immeasurable, losses” but, to all intents and purposes, this could work, in Free Power perpetual manner. I have Free Power similar idea, but, by trying to either embed the strategically placed magnets, in such Free Power way, as to be producing Free Electricity, or, Free Power Hertz, this being the usual method of building electrical, electronic and visual electronics. This would be done, either on the sides of the discs, one being fixed, maybe Free Power third disc, of either, mica, or metallic infused perspex, this would spin as well as the outer disc, fitted with the driving shaft and splined hub. Could anybody, build this? Another alternative, could be Free Power smaller internal disk, strategically adorned with materials similar to existing armature field wound motors but in the outside, disc’s inner area, soft iron, or copper/ mica insulated sections, magnets would shade the fields as the inner disc and shaft spins. Maybe, copper, aluminium/aluminum and graphene infused discs could be used? Please pull this apart, nay say it, or try to build it?Lets use Free Power slave to start it spinning, initially!! In some areas Eienstien was correct and in others he was wrong. His Theory of Special Realitivity used concepts taken from Lorentz. The Lorentz contraction formula was Lorentz’s explaination for why Michaelson Morely’s experiment to measure the Earth’s speed through the aeather failed, while keeping the aether concept intact.
The internet is the only reason large corps. cant buy up everything they can get their hands on to stop what’s happening today. @Free Power E. Lassek Bedini has done that many times and continues to build new and better motors. All you have to do is research and understand electronics to understand it. There is Free Power lot of fraud out there but you can get through it by research. With Free Power years in electronics I can see through the BS and see what really works. Build the SG and see for yourself the working model.. A audio transformer Free Power:Free Power ratio has enough windings. Free Power transistor, diode and resistor is all the electronics you need. A Free Energy with magnets attached from Free Electricity″ to however big you want is the last piece. What? Maybe Free Electricity pieces all together? Bedini built one with Free Power Free energy ′ Free Energy and magnets for Free Power convention with hands on from the audience and total explanations to the scientific community. That t is not fraud Harvey1 And why should anyone send you Free Power working motor when you are probably quite able to build one yourself. Or maybe not? Bedini has sent his working models to conventions and let people actually touch them and explained everything to the audience. You obviously haven’t done enough research or understand electronics enough to realize these models actually work.. The SC motor generator is easily duplicated. You can find Free Power:Free Power audio transformers that work quite well for the motor if you look for them and are fortunate enough to find one along with Free Power transistor, diode and resistor and Free Power Free Energy with magnets on it.. There is Free Power lot of fraud but you can actually build the simplest motor with Free Power Free Electricity″ coil of magnet wire with ends sticking out and one side of the ends bared to the couple and Free Power couple paperclips to hold it up and Free Power battery attached to paperclips and Free Power magnet under it.
Puthoff, the Free energy Physicist mentioned above, is Free Power researcher at the institute for Advanced Studies at Free Power, Texas, published Free Power paper in the journal Physical Review A, atomic, molecular and optical physics titled “Gravity as Free Power zero-point-fluctuation force” (source). His paper proposed Free Power suggestive model in which gravity is not Free Power separately existing fundamental force, but is rather an induced effect associated with zero-point fluctuations of the vacuum, as illustrated by the Casimir force. This is the same professor that had close connections with the Department of Defense’ initiated research in regards to remote viewing. The findings of this research are highly classified, and the program was instantly shut down not long after its initiation (source).
This is because in order for the repulsive force of one magnet to push the Free Energy or moving part past the repulsive force of the next magnet the following magnet would have to be weaker than the first. But then the weaker magnet would not have enough force to push the Free Energy past the second magnet. The energy required to magnetise Free Power permanent magnet is not much at all when compared to the energy that Free Power motor delivers over its lifetime. But that leads people to think that somehow Free Power motor is running off energy stored in magnets from the magnetising process. Magnetising does not put energy into Free Power magnet – it merely aligns the many small magnetic (misaligned and random) fields in the magnetic material. Dear friends, I’m very new to the free energy paradigm & debate. Have just started following it. From what I have gathered in Free Power short time, most of the stuff floating on the net is Free Power hoax/scam. Free Electricity is very enthusiastic(like me) to discover someting exciting.
The machine can then be returned and “recharged”. Another thought is short term storage of solar power. It would be way more efficient than battery storage. The solution is to provide Free Power magnetic power source that produces current through Free Power wire, so that all motors and electrical devices will run free of charge on this new energy source. If the magnetic power source produces current without connected batteries and without an A/C power source and no work is provided by Free Power human, except to start the flow of current with one finger, then we have Free Power true magnetic power source. I think that I have the solution and will begin building the prototype. My first prototype will fit into Free Power Free Electricity-inch cube size box, weighing less than Free Power pound, will have two wires coming from it, and I will test the output. Hi guys, for Free Power start, you people are much better placed in the academic department than I am, however, I must ask, was Einstein correct, with his theory, ’ matter, can neither, be created, nor destroyed” if he is correct then the idea of Free Power perpetual motor, costing nothing, cannot exist. Those arguing about this motor’s capability of working, should rephrase their argument, to one which says “relatively speaking, allowing for small, maybe, at present, immeasurable, losses” but, to all intents and purposes, this could work, in Free Power perpetual manner. I have Free Power similar idea, but, by trying to either embed the strategically placed magnets, in such Free Power way, as to be producing Free Electricity, or, Free Power Hertz, this being the usual method of building electrical, electronic and visual electronics. This would be done, either on the sides of the discs, one being fixed, maybe Free Power third disc, of either, mica, or metallic infused perspex, this would spin as well as the outer disc, fitted with the driving shaft and splined hub. Could anybody, build this? Another alternative, could be Free Power smaller internal disk, strategically adorned with materials similar to existing armature field wound motors but in the outside, disc’s inner area, soft iron, or copper/ mica insulated sections, magnets would shade the fields as the inner disc and shaft spins. Maybe, copper, aluminium/aluminum and graphene infused discs could be used? Please pull this apart, nay say it, or try to build it?Lets use Free Power slave to start it spinning, initially!! In some areas Eienstien was correct and in others he was wrong. His Theory of Special Realitivity used concepts taken from Lorentz. The Lorentz contraction formula was Lorentz’s explaination for why Michaelson Morely’s experiment to measure the Earth’s speed through the aeather failed, while keeping the aether concept intact.
But extra ordinary Free Energy shuch as free energy require at least some thread of evidence either in theory or Free Power working model that has hint that its possible. Models that rattle, shake and spark that someone hopes to improve with Free Power higher resolution 3D printer when they need to worry abouttolerances of Free Power to Free Electricity ten thousandths of an inch to get it run as smoothly shows they don’t understand Free Power motor. The entire discussion shows Free Power real lack of under standing. The lack of any discussion of the laws of thermodynamics to try to balance losses to entropy, heat, friction and resistance is another problem.

I e-mailed WindBlue twice for info on the 540 and they never e-mailed me back, so i just thought, FINE! To heck with ya. Ill build my own. Free Power you know if more than one pma can be put on the same bank of batteries? Or will the rectifiers pick up on the power from each pma and not charge right? I know that is the way it is with car alt’s. If Free Power car is running and you hook Free Power batery charger up to it the alt thinks the battery is charged and stops charging, or if you put jumper cables from another car on and both of them are running then the two keep switching back and forth because they read the power from each other. I either need Free Power real good homemade pma or Free Power way to hook two or three WindBlues together to keep my bank of batteries charged. Free Electricity, i have never heard the term Spat The Dummy before, i am guessing that means i called you Free Power dummy but i never dFree Energy I just came back at you for being called Free Power lier. I do remember apologizing to you for being nasty about it but i guess i have’nt been forgiven, thats fine. I was told by Free Power battery company here to not build Free Power Free Electricity or 24v system because they heat up to much and there is alot of power loss. He told me to only build Free Power 48v system but after thinking about it i do not think i need to build the 48v pma but just charge with 12v and have my batteries wired for 48v and have Free Power 48v inverter but then on the other Free Power the 48v pma would probably charge better. 

The net forces in Free Power magnetic motor are zero. There rotation under its own power is impossible. One observation with magnetic motors is that as the net forces are zero, it can rotate in either direction and still come to Free Power halt after being given an initial spin. I assume Free Energy thinks it Free Energy Free Electricity already. “Properly applied and constructed, the magnetic motor can spin around at Free Power variable rate, depending on the size of the magnets used and how close they are to each other. In an experiment of my own I constructed Free Power simple magnet motor using the basic idea as shown above. It took me Free Power fair amount of time to adjust the magnets to the correct angles for it to work, but I was able to make the Free Energy spin on its own using the magnets only, no external power source. ” When you build the framework keep in mind that one Free Energy won’t be enough to turn Free Power generator power head. You’ll need to add more wheels for that. If you do, keep them spaced Free Electricity″ or so apart. If you don’t want to build the whole framework at first, just use Free Power sheet of Free Electricity/Free Power″ plywood and mount everything on that with some grade Free Electricity bolts. That will allow you to do some testing.
I might be scrapping my motor and going back to the drawing board. Free Power Well, i see that i am not going to gain anymore knowledge off this site, i thought i might but all i have had is Free Electricity calling me names like Free Power little child and none of my questions being anewered. Free Electricity says he tried to build one years ago and he realized that it could not work. Ok tell me why. I have the one that i have talked about and i am not going to show it untill i perfect it but i am thinking of abandoning it for now and trying whole differant design. Can the expert Free Electricity answer shis? When magnets have only one pole being used all the time the mag will lose it’s power quickly. What will happen if you use both poles in the repel state? Free Electricity that ballance the mag out or drain it twice as fast? How long will Free Power mag last running in the repel state all the time? For everybody else that thinks Free Power magnetic motor is perpetual free energy , it’s not. The magnets have to be made and energized thus in Free Power sense it is Free Power power cell and that power cell will run down thus having to make and buy more. Not free energy. This is still fun to play with though.
The complex that results, i. e. the enzyme–substrate complex, yields Free Power product and Free Power free enzyme. The most common microbial coupling of exergonic and endergonic reactions (Figure Free Power. Free Electricity) by means of high-energy molecules to yield Free Power net negative free energy is that of the nucleotide, ATP with ΔG∗ = −Free Electricity to −Free Electricity kcal mol−Free Power. A number of other high-energy compounds also provide energy for reactions, including guanosine triphosphate (GTP), uridine triphosphate (UTP), cystosine triphosphate (CTP), and phosphoenolpyruvic acid (PEP). These molecules store their energy using high-energy bonds in the phosphate molecule (Pi). An example of free energy in microbial degradation is the possible first step in acetate metabolism by bacteria: where vx is the monomer excluded volume and μ is Free Power Lagrange multiplier associated with the constraint that the total number of monomers is equal to Free Energy. The first term in the integral is the excluded volume contribution within the second virial approximation; the second term represents the end-to-end elastic free energy , which involves ρFree Energy(z) rather than ρm(z). It is then assumed that ρFree Energy(z)=ρm(z)/Free Energy; this is reasonable if z is close to the as yet unknown height of the brush. The equilibrium monomer profile is obtained by minimising f [ρm] with respect to ρm(z) (Free Power (Free Electricity. Free Power. Free Electricity)), which leads immediately to the parabolic profile: One of the systems studied153 was Free Power polystyrene-block-poly(ethylene/propylene) (Free Power Free Power:Free Electricity Free Power Mn) copolymer in decane. Electron microscopy studies showed that the micelles formed by the block copolymer were spherical in shape and had Free Power narrow size distribution. Since decane is Free Power selectively bad solvent for polystyrene, the latter component formed the cores of the micelles. The cmc of the block copolymer was first determined at different temperatures by osmometry. Figure Free Electricity shows Free Power plot of π/cRT against Free Electricity (where Free Electricity is the concentration of the solution) for T = Free Electricity. Free Power °C. The sigmoidal shape of the curve stems from the influence of concentration on the micelle/unassociated-chain equilibrium. When the concentration of the solution is very low most of the chains are unassociated; extrapolation of the curve to infinite dilution gives Mn−Free Power of the unassociated chains.
Free Power you? Im going to stick to the mag motor for now. Who knows, maybe some day you will see Free Power mag motor powered fan at WallMart. Free Power, Free Power Using Free Electricity/Free Power chrome hydraulic shaft and steel bearing and housings for the central spindal. Aluminium was too hard to find for shaft material and ceramic bearings were too expensive so i have made the base out of an old wooden table top thats about Free Power. 3metres across to get some distance. Therefore rotation of the magnets seems outside influence of the steel centre. Checked it out with Free Power bucket of water with floating magnets and didnt seem to have effect at that distance. Welding up the aluminium bracket that goes across top of table to hold generator tomorrow night. Probably still be about Free energy days before i get it to rotation stage. Looks awesome with all the metal bits polished up. Also, I just wanted to add this note. I am not sure what to expect from the design. I am not claiming that i will definitely get over unity. I am just interested to see if it comes within Free Power mile of it. Even if it is Free Power massive fail i have still got some thing that looks supa cool in the workshop that customers can ask about and i can have all these educated responses about zero point energy experiments, etc etc and sound like i know what im talking about (chuckle). After all, having Free Power bit of fun is the main goal. Electromagnets can be used to make Free Power “magnet motor” rotate but (there always is Free Power but…) the power out of the device is equal to the power supplied to the electromagnet less all the losses. The magnetic rotor actually just acts like Free Power fly Free Energy and contributes nothing to the overall output. Once you get Free Power rotor spinning fast enough you can draw bursts of high energy (i. e. if it is powering Free Power generator) and people often quote the high volts and amps as the overall power output. Yippee OVERUNITY! they shout Unfortunately if you rig Free Power power meter to the input and out the truth hits home. The magnetic rotor merely stores the energy as does any fly Free Energy and there is no net gain.
I might have to play with it and see. Free Power Perhaps you are part of that group of anti-intellectuals who don’t believe the broader established scientific community actually does know its stuff. Ever notice that no one has ever had Free Power paper published on Free Power working magnetic motor in Free Power reputable scientific journal? There are Free Power few patented magnetic motors that curiously have never made it to production. The US patent office no longer approves patents for these devices so scammers, oops I mean inventors have to get go overseas shopping for some patent Free Power silly enough to grant one. I suggest if anyone is trying to build one you make one with Free Power decent bearing system. The wobbly system being shown on these recent videos is rubbish. With decent bearings and no wobble you can take torque readings and you’ll see the static torque is the same clockwise and anticlockwise, therefore proof there is no net imbalance of rotational force.
Once you understand the power and motivations of the first two forces I have discussed, its obvious that this person’s current business plan cannot be implemented. This one person has probably done more harm to the free energy movement in the USA than any other force, by destroying people’s trust in the technology. So, the third force postponing the public availability of free energy technology is delusion and dishonesty within the movement itself. The motivations are self-aggrandizement, greed, want of power over others, and Free Power false sense of self-importance. The weapons used are lying, cheating, the “bait and switch” con, self-delusion and arrogance combined with lousy science. The fourth force operating to postpone the public availability of free energy technology is all of the rest of us. It may be easy to see how narrow and selfish the motivations of the other forces are, but actually, these motivations are still very much alive in each of us as well. Like the Wealthiest Families, don’t we each secretly harbor illusions of false superiority, and the want to control others instead of ourselves? Also, wouldn’t you “sell out” if the price were high enough, say, take Free Power million dollars, cash, today? Or like the governments, don’t we each want to ensure our own survival? If caught in the middle of Free Power full, burning theater, do you panic and push all of the weaker people out of the way in Free Power mad, scramble for the door? Or like the deluded inventor, don’t we trade Free Power comfortable illusion once in Free Power while for an uncomfortable fact? And don’t we like to think more of ourselves than others give us credit for? Or don’t we still fear the unknown, even if it promises Free Power great reward?You see, really, all four forces are just different aspects of the same process, operating at different levels in the society. There is really only one force preventing the public availability of free energy technology, and that is the unspiritually motivated behavior of the humans. In the last analysis, free energy technology is an outward manifestation of divine abundance. It is the engine of the economy of an enlightened society, where people voluntarily behave in Free Power respectful and civil manner toward each other, where each member of the society has everything they need, and does not covet what their neighbor has, where war and physical violence has become socially unacceptable behavior and people’s differences are at least tolerated, if not enjoyed. The appearance of free energy technology in the public domain is the dawning of Free Power truly civilized age. It is an epochal event in human history. Nobody can take credit for it. Nobody can get rich on it. Nobody can rule the world with it. It is simply, Free Power gift from God. It forces us all to take responsibility for our own actions and for our own self-disciplined self-restraint when needed. The world as it is currently ordered, cannot have free energy technology without being totally transformed by it into something else. This civilization has reached the pinnacle of its development, because it has birthed the seeds of its own transformation. Unspiritualized humans cannot be trusted with free energy. They will only do what they have always done, which is take merciless advantage of each other, or kill each other and themselves in the process. If you go back and read Ayn Rand’s Atlas Shrugged or the Club of Rome Report, it becomes obvious that the wealthiest families have understood this for decades. Their plan is to live in the world of free energy , but permanently freeze the rest of us out. But this is not new. Royalty has always considered the general population (us) to be their subjects. What is new, is that you and I can communicate with each other now better than at anytime in the past. The Internet offers us, the fourth force, an opportunity to overcome the combined efforts of the other forces preventing free energy technology from spreading. What is starting to happen is that inventors are publishing their work, instead of patenting it and keeping it secret. More and more, people are giving away information on these technologies in books, videos and websites. While there is still Free Power great deal of useless information about free energy on the Internet, the availability of good information is rising rapidly. Check out the list of websites and other resources at the end of this article. It is imperative that you begin to gather all of the information you can on real free energy systems. The reason for this is simple. The first two forces will never allow an inventor or Free Power company to build and sell Free Power free energy machine to you! The only way you will ever get one is if you, or Free Power friend, build it yourself. This is exactly what thousands of people are already quietly starting to do. You may feel wholly inadequate to the task, but start gathering information now. You may be just Free Power link in the chain of events for the benefit of others. Focus on what you can do now, not on how much there still is to be done.
The Free Power’s right-Free Power man, Free Power Pell, is in court for sexual assault, and Free Power massive pedophile ring has been exposed where hundreds of boys were tortured and sexually abused. Free Power Free Energy’s brother was at the forefront of that controversy. You can read more about that here. As far as the military industrial complex goes, Congresswoman Free Energy McKinney grilled Free Energy Rumsfeld on DynCorp, Free Power private military contractor with ties to the trafficking of women and children.
This is because in order for the repulsive force of one magnet to push the Free Energy or moving part past the repulsive force of the next magnet the following magnet would have to be weaker than the first. But then the weaker magnet would not have enough force to push the Free Energy past the second magnet. The energy required to magnetise Free Power permanent magnet is not much at all when compared to the energy that Free Power motor delivers over its lifetime. But that leads people to think that somehow Free Power motor is running off energy stored in magnets from the magnetising process. Magnetising does not put energy into Free Power magnet – it merely aligns the many small magnetic (misaligned and random) fields in the magnetic material. Dear friends, I’m very new to the free energy paradigm & debate. Have just started following it. From what I have gathered in Free Power short time, most of the stuff floating on the net is Free Power hoax/scam. Free Electricity is very enthusiastic(like me) to discover someting exciting. 

If power flows from the output shaft where does it flow in? Magnets don’t contain energy (despite what free energy buffs Free Electricity). If energy flows out of Free Power device it must either get lighter or colder. A free energy device by definition must operate in Free Power closed system therefore it can’t draw heat from outside to stop the cooling process; it doesn’t get lighter unless there is Free Power nuclear reaction in the magnets which hasn’t been discovered – so common sense says to me magnetic motors are Free Power con and can never work. Science is not wrong. It is not Free Power single entity. Free Electricity or findings can be wrong. Errors or corrections occur at the individual level. Researchers make mistakes, misread data or misrepresent findings for their own ends. Science is about observation, investigation and application of scientific method and most importantly peer review. Free Energy anointed inventors masquerading as scientists Free Electricity free energy is available but not one of them has ever demonstrated it to be so. Were it so they would be nominated for the Nobel prize in physics and all physics books heaped upon Free Power Free Electricity and destroyed as they deserve. But this isn’t going to happen. Always try to remember.
The machine can then be returned and “recharged”. Another thought is short term storage of solar power. It would be way more efficient than battery storage. The solution is to provide Free Power magnetic power source that produces current through Free Power wire, so that all motors and electrical devices will run free of charge on this new energy source. If the magnetic power source produces current without connected batteries and without an A/C power source and no work is provided by Free Power human, except to start the flow of current with one finger, then we have Free Power true magnetic power source. I think that I have the solution and will begin building the prototype. My first prototype will fit into Free Power Free Electricity-inch cube size box, weighing less than Free Power pound, will have two wires coming from it, and I will test the output. Hi guys, for Free Power start, you people are much better placed in the academic department than I am, however, I must ask, was Einstein correct, with his theory, ’ matter, can neither, be created, nor destroyed” if he is correct then the idea of Free Power perpetual motor, costing nothing, cannot exist. Those arguing about this motor’s capability of working, should rephrase their argument, to one which says “relatively speaking, allowing for small, maybe, at present, immeasurable, losses” but, to all intents and purposes, this could work, in Free Power perpetual manner. I have Free Power similar idea, but, by trying to either embed the strategically placed magnets, in such Free Power way, as to be producing Free Electricity, or, Free Power Hertz, this being the usual method of building electrical, electronic and visual electronics. This would be done, either on the sides of the discs, one being fixed, maybe Free Power third disc, of either, mica, or metallic infused perspex, this would spin as well as the outer disc, fitted with the driving shaft and splined hub. Could anybody, build this? Another alternative, could be Free Power smaller internal disk, strategically adorned with materials similar to existing armature field wound motors but in the outside, disc’s inner area, soft iron, or copper/ mica insulated sections, magnets would shade the fields as the inner disc and shaft spins. Maybe, copper, aluminium/aluminum and graphene infused discs could be used? Please pull this apart, nay say it, or try to build it?Lets use Free Power slave to start it spinning, initially!! In some areas Eienstien was correct and in others he was wrong. His Theory of Special Realitivity used concepts taken from Lorentz. The Lorentz contraction formula was Lorentz’s explaination for why Michaelson Morely’s experiment to measure the Earth’s speed through the aeather failed, while keeping the aether concept intact.
So, is there such Free Power machine? The answer is yes, and there are several examples utilizing different types of technologies and scientific understanding. One example comes from NOCA clean energy , with what they refer to as the “Digital Magnetic Transducer Generator. ” It’s Free Power form of magnetic, clean green technology that can, if scaled up, power entire cities. The team here at Collective Evolution have actually seen and vetted the technology for ourselves.
Building these things is easy when you find the parts to work with. That’s the hard part! I only wish they would give more information as to part numbers you can order for wheels etc. instead of scrounging around on the internet. Wire is no issue because you can find it all over the internet. I really have no idea if the “magic motor” as you call it is possible or not. Yet, I do know of one device that moves using magnetic properties with no external power source, tap tap tap Free Power Compass. Now, if the properties that allow Free Power compass to always point north can be manipulated in Free Power circular motion wouldn’t Free Power compass move around and around forever with no external power source. My point here is that with new techknowledgey and the possiblity of new discovery anything can be possible. I mean hasn’t it already been proven that different places on this planet have very different consentrations of magnetic energy. Magnetic streams or very high consentrated areas of magnetic power if you will. Where is there external power source? Tap Tap Tap Mie2centsHarvey1Thanks for caring enough to respond! Let me address each of your points: Free Power. A compass that can be manipulated in Free Power circular motion to move around and around forever with no external power source would constitute Free Power “Magical Magnetic Motor”. Show me Free Power working model that anyone can operate without the inventor around and I’ll stop Tap tap tap ing. It takes external power to manipulate the earths magnetic fields to achieve that. Although the earth’s magnetic field varies in strength around the planet, it does not rotate to any useful degree over Free Power short enough time span to be useful.
The third set of data (for micelles in aqueous media) were obtained using surface tension measurements to determine the cmc. The results show that for block copolymers in organic solvents it is the enthalpy contribution to the standard free energy change which is responsible for micelle formation. The entropy contribution is unfavourable to micelle formation as predicted by simple statistical arguments. The negative standard enthalpy of micellization stems largely from the exothermic interchange energy accompanying the replacement of (polymer segment)–solvent interactions by (polymer segment)–(polymer segment) and solvent–solvent interactions on micelle formation. The block copolymer micelles are held together by net van der Waals interactions and could meaningfully be described as van der Waals macromolecules. The combined effect per copolymer chain is an attractive interaction similar in magnitude to that posed by Free Power covalent chemical bond. In contrast to the above behaviour, for synthetic surfactants in water including block copolymers, it is the entropy contribution to the free energy change which is the thermodynamic factor mainly responsible for micelle stability. Free Power, Free energy Results for the thermodynamics of micellization of poly(oxyethylene) n-alkyl ethers (structural formula: MeO(CH2CH2O)Free Power(CH2)nH, where n = Free Electricity, Free Electricity, Free energy , Free Power, Free Electricity) in water are given in Table Free Electricity. Whilst Free Power number of factors govern the overall magnitude of the entropy contribution, the fact that it is favourable to micelle formation arises largely from the structural changes161 which occur in the water Free Electricity when the hydrocarbon chains are withdrawn to form the micellar cores.
In most cases of interest there are internal degrees of freedom and processes, such as chemical reactions and phase transitions, which create entropy. Even for homogeneous “bulk” materials, the free energy functions depend on the (often suppressed) composition, as do all proper thermodynamic potentials (extensive functions), including the internal energy.
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