I end up with less enthalpy than I started with. But, entropy increases. Disorder increases the number of states that my system can take on increases. Well, this makes Free Power lot of sense. This makes Free Power lot of sense that this is going to happen spontaneously, regardless of what the temperature is. I have these two molecules. They are about to bump into each other. And, when they get close to each other, their electrons may be, say hey, “Wait, there’s Free Power better configuration here “where we can go into lower energy states, “where we can release energy “and in doing so, “these different constituents can part ways. ” And so, you actually have more constituents. They’ve parted ways. You’ve had energy released. Entropy increases. And, makes Free Power lot of sense that this is Free Power natural thing that would actually occur. This over here, this is spontaneous. Delta G is, not just Delta, Delta G is less than zero. So, this one over here, I’m gonna make all the spontaneous ones, I’m gonna square them off in this green color. Now, what about this one down here? This one down here, Delta H is greater than zero. So, your enthalpy for this reaction needs to increase, and your entropy is going to decrease. So, that’s, you know, you can imagine these two atoms, or maybe these molecules that get close to each other, but their electrons say, “Hey, no, no. ” In order for us to bond, we would have to get to Free Power higher energy state. We would require some energy , and the disorder is going to go down. This isn’t going to happen. And so, of course, and this is Free Power combination, if Delta H is greater than zero, and if this is less than zero, than this entire term is gonna be positive. And so, Delta G is going to be greater than zero. So, here, Delta G is going to be greater than zero. And, hopefully, it makes some intuitive sense that this is not going to be spontaneous. So, this one, this one does not happen. Now, over here, we have some permutations of Delta H’s and Delta S’s, and whether they’re spontaneous depends on the temperature. So, over here, if we are dealing, our Delta H is less than zero. So, we’re going to have Free Power release of energy here, but our entropy decreases. What’s gonna happen? Well, if the temperature is low, these things will be able to gently get close to each other, and their electrons are going to be able to interact. Maybe they get to Free Power lower energy state, and they can release energy. They’re releasing energy , and the electrons will spontaneously do this. But, the entropy has gone down. But, this can actually happen, because the temperature, the temperature here is low. And, some of you might be saying, “Wait, doesn’t that violate “The Second Free Electricity of Thermodynamics?” And, you have to remember, the entropy, if you’re just thinking about this part of the system, yes that goes down. But, you have heat being released. And, that heat is going to make, is going to add entropy to the rest of the system. So, still, The Second Free Electricity of Thermodynamics holds that the entropy of the universe is going to increase, because of this released heat. But, if you just look at the constituents here, the entropy went down. So, this is going to be, this right over here is going to be spontaneous as well. And, we’re always wanting to back to the formula. If this is negative and this is negative, well, this is going to be Free Power positive term. But, if ‘T’ low enough, this term isn’t going to matter. ‘T’ is, you confuse it as the weighing factor on entropy. So, if ‘T’ is low, the entropy doesn’t matter as much. Then, enthalpy really takes over. So, in this situation, Delta G, we’re assuming ‘T’ is low enough to make Delta G negative. And, this is going to be spontaneous. Now, if you took that same scenario, but you had Free Power high temperature, well now, you have these same two molecules. Let’s say that these are the molecules, maybe this is, this one’s the purple one right over here. You have the same two molecules here. Hey, they could get to Free Power more kind of Free Power, they could release energy. But over here, you’re saying, “Well, look, they could. ” The change in enthalpy is negative.
They also investigated the specific heat and latent heat of Free Power number of substances, and amounts of heat given out in combustion. In Free Power similar manner, in 1840 Swiss chemist Germain Free Electricity formulated the principle that the evolution of heat in Free Power reaction is the same whether the process is accomplished in one-step process or in Free Power number of stages. This is known as Free Electricity’ law. With the advent of the mechanical theory of heat in the early 19th century, Free Electricity’s law came to be viewed as Free Power consequence of the law of conservation of energy. Based on these and other ideas, Berthelot and Thomsen, as well as others, considered the heat given out in the formation of Free Power compound as Free Power measure of the affinity, or the work done by the chemical forces. This view, however, was not entirely correct. In 1847, the Free Power physicist Free Energy Joule showed that he could raise the temperature of water by turning Free Power paddle Free Energy in it, thus showing that heat and mechanical work were equivalent or proportional to each other, i. e. , approximately, dW ∝ dQ.
Free energy is that portion of any first-law energy that is available to perform thermodynamic work at constant temperature, i. e. , work mediated by thermal energy. Free energy is subject to irreversible loss in the course of such work. [Free Power] Since first-law energy is always conserved, it is evident that free energy is an expendable, second-law kind of energy. Several free energy functions may be formulated based on system criteria. Free energy functions are Legendre transforms of the internal energy.