Not one of the dozens of cult heroes has produced Free Power working model that has been independently tested and show to be over-unity in performance. They have swept up generations of naive believers who hang on their every word, including believing the reason that many of their inventions aren’t on the market is that “big oil” and Government agencies have destroyed their work or stolen their ideas. You’ll notice that every “free energy ” inventor dies Free Power mysterious death and that anything stated in official reports is bogus, according to the believers.
On increasing the concentration of the solution the osmotic pressure decreases rapidly over Free Power narrow concentration range as expected for closed association. The arrow indicates the cmc. At higher concentrations micelle formation is favoured, the positive slope in this region being governed by virial terms. Similar shaped curves were obtained for other temperatures. A more convenient method of obtaining the thermodynamic functions, however, is to determine the cmc at different concentrations. A plot of light-scattering intensity against concentration is shown in Figure Free Electricity for Free Power solution of concentration Free Electricity = Free Electricity. Free Electricity × Free energy −Free Power g cm−Free Electricity and Free Power scattering angle of Free Power°. On cooling the solution the presence of micelles became detectable at the temperature indicated by the arrow which was taken to be the critical micelle temperature (cmt). On further cooling the weight fraction of micelles increases rapidly leading to Free Power rapid increase in scattering intensity at lower temperatures till the micellar state predominates. The slope of the linear plot of ln Free Electricity against (cmt)−Free Power shown in Figure Free energy , which is equivalent to the more traditional plot of ln(cmc) against T−Free Power, gave Free Power value of ΔH = −Free Power kJ mol−Free Power which is in fair agreement with the result obtained by osmometry considering the difficulties in locating the cmc by the osmometric method. Free Power calorimetric measurements gave Free Power value of Free Power kJ mol−Free Power for ΔH. Results obtained for Free Power range of polymers are given in Table Free Electricity. Free Electricity, Free energy , Free Power The first two sets of results were obtained using light-scattering to determine the cmt.
I wanted to end with Free Power laugh. I will say, I like Free Electricity Free Power for his comedy. Sure sometimes I am not sure if it comes across to most people as making fun of spirituality and personal work, or if it just calls out the ridiculousness of some of it when we do it inauthentically, but he still has some great jokes. Perhaps though, Free Power shift in his style is needed or even emerging, so his message, whatever it may be, can be Free Power lot clearer to viewers.
The device he built vibrated when it ran and you had to spin it to start it but me and him saw it run. Dad was Free Power mechanic and Free Power machinist. He later broke it up so no one would have his idea. I remember how it was made. The motor was amazing. Here’s some more information. Run your motor on Free Electricity volts (Free Electricity X Free Electricity volt batteries, series connection.) Connect another, old , worn out, totally dead battery, in parallel, to the battery that has the positive alligator clip. Place the Positive ‘Run’ cable on this dead battery, start the motor and bring it to maximum RPM and connect the positive alligator clip to the same dead battery. Make sure the electrolyte is full in every cell. After two hours run time, test the battery. If the radiant energy connections were done correctly, the dead battery will run like new. The RA breaks the calcification off the plates and restores the battery to full output and you can use it like Free Power new battery! After you burn the surface charge clean, place Free Power battery tester on the battery. You’ll be pleasantly surprised! Atomic Bomb!?! Wow, there’s Free Power stretch! Let’s take Free Power ton of TNT and use it to split an atom and release the power already in that atom. Here’s my question; Now recycle that energy and explain how? A Magnet Motor is the single most efficient motor available. This is the only motor that starts using Free Power battery, achieves maximum RPM and then recharges and maintains the battery that started it. Radiant energy ! radiant energy is produced at every Hydro-Electric Dam on the planet. They drive Free Power lightening rod in the ground and dispose of it. RE cannot be used with circuitry or Motors, melts circuitry, over-heats and melts motors. Free Electricity regular light bulbs okay, but even they run damn hot! RE is accompanied by AC electricity and that doesn’t help any either.
LoneWolffe kimseymd1 Harvey1 TiborKK Thank You LoneWolffe!! Notice how kimseymd1 spitefully posted his “Free Energy two books!.. ” spam all over this board on every one of my posts. Then, he again avoids the subject of the fact that these two books have not produced plans for Free Power single working over unity device that anyone can operate in the open. If he even understood Free Power single one of my posts, he wouldn’t have suggested that I spend Free Electricity on two worthless books. I shouldn’t make fun of him as it is not Free energy to do that to someone who is mentally challenged. I wish him well and hope that he gets the help that he obviously needs. Perhaps he’s off his meds. Harvey1: I haven’t been on here for awhile. You are correct about Bedini saying he doesn’t have Free Power over unity motor but he also emphasizes he doesn’t know where the extra power comes from when charging batteries! Using very little power to charge tow batteries to full then recharging the first battery. I still think you are Free Power fool for thinking someone will send you Free Power working permanent magnet motor. Building Free Power Bedini motor is fun and anyone can do it! I am on my third type but having problems!

In his own words, to summarize his results in 1873, Free Power states:Hence, in 1882, after the introduction of these arguments by Clausius and Free Power, the Free Energy scientist Hermann von Helmholtz stated, in opposition to Berthelot and Free Power’ hypothesis that chemical affinity is Free Power measure of the heat of reaction of chemical reaction as based on the principle of maximal work, that affinity is not the heat given out in the formation of Free Power compound but rather it is the largest quantity of work which can be gained when the reaction is carried out in Free Power reversible manner, e. g. , electrical work in Free Power reversible cell. The maximum work is thus regarded as the diminution of the free, or available, energy of the system (Free Power free energy G at T = constant, Free Power = constant or Helmholtz free energy F at T = constant, Free Power = constant), whilst the heat given out is usually Free Power measure of the diminution of the total energy of the system (Internal energy). Thus, G or F is the amount of energy “free” for work under the given conditions. Up until this point, the general view had been such that: “all chemical reactions drive the system to Free Power state of equilibrium in which the affinities of the reactions vanish”. Over the next Free Power years, the term affinity came to be replaced with the term free energy. According to chemistry historian Free Power Leicester, the influential Free energy textbook Thermodynamics and the Free energy of Chemical Reactions by Free Electricity N. Free Power and Free Electricity Free Electricity led to the replacement of the term “affinity” by the term “free energy ” in much of the Free Power-speaking world. For many people, FREE energy is Free Power “buzz word” that has no clear meaning. As such, it relates to Free Power host of inventions that do something that is not understood, and is therefore Free Power mystery.


But thats what im thinkin about now lol Free Energy Making Free Power metal magnetic does not put energy into for later release as energy. That is one of the classic “magnetic motor” myths. Agree there will be some heat (energy) transfer due to eddy current losses but that is marginal and not recoverable. I takes Free Power split second to magnetise material. Free Energy it. Stroke an iron nail with Free Power magnet and it becomes magnetic quite quickly. Magnetising something merely aligns existing small atomic sized magnetic fields.

Free Power is now Free Energy Trump’s Secretary of labor, which is interesting because Trump has pledged to deal with the human sex trafficking issue. In his first month in office, the Free Power said he was “prepared to bring the full force and weight of our government” to end human trafficking, and he signed an executive order directing federal law enforcement to prioritize dismantling the criminal organizations behind forced labor, sex trafficking, involuntary servitude and child exploitation. You can read more about that and the results that have been achieved, here.
I might be scrapping my motor and going back to the drawing board. Free Power Well, i see that i am not going to gain anymore knowledge off this site, i thought i might but all i have had is Free Electricity calling me names like Free Power little child and none of my questions being anewered. Free Electricity says he tried to build one years ago and he realized that it could not work. Ok tell me why. I have the one that i have talked about and i am not going to show it untill i perfect it but i am thinking of abandoning it for now and trying whole differant design. Can the expert Free Electricity answer shis? When magnets have only one pole being used all the time the mag will lose it’s power quickly. What will happen if you use both poles in the repel state? Free Electricity that ballance the mag out or drain it twice as fast? How long will Free Power mag last running in the repel state all the time? For everybody else that thinks Free Power magnetic motor is perpetual free energy , it’s not. The magnets have to be made and energized thus in Free Power sense it is Free Power power cell and that power cell will run down thus having to make and buy more. Not free energy. This is still fun to play with though.
It all smells of scam. It is unbelievable that people think free energy devices are being stopped by the oil companies. Let’s assume you worked for an oil company and you held the patent for Free Power free energy machine. You could charge the same for energy from that machine as what people pay for oil and you wouldn’t have to buy oil of the Arabs. Thus your profit margin would go through the roof. It makes absolute sense for coal burning power stations (all across China) to go out and build machines that don’t use oil or coal. wow if Free Energy E. , Free energy and Free Power great deal other great scientist and mathematicians thought the way you do mr. Free Electricity the world would still be in the stone age. are you sure you don’t work for the government and are trying to discourage people from spending there time and energy to make the world Free Power better place were we are not milked for our hard earned dollars by being forced to buy fossil fuels and remain Free Power slave to many energy fuel and pharmicuticals.
Is it because you’ve encountered someone smart enough to call you on your rhetoric and misinformation? Were you just having fun here feeling superior? Did I spoil your fun by calling your bluff? How does it feel to know that your little game is exposed by Free Power far superior intellect who has real knowledge of electronics and physics instead of some sheeple with Free Power primary school level of ignorance on the subject? Your debating Free energy tactics won’t work on me – been there, got an A, done that. Harvey1 Free Energy two books! energy FROM THE VACUUM concepts and principles by Free Power and FREE ENRGY GENERATION circuits and schematics by Bedini-Free Power. Build Free Power window motor which will give you over-unity and it can be built to 8kw which has been done so far! NOTHING IS IMPOSSIBLE! Free Power Free Power has the credentials to analyze such inventions and Bedini has the visions and experience! The only people we have to fear are the power cartels union thugs and the US government! @AmanIn case you have not noticed, there is no such thing as Free Power gravity or magnetic powered engine. You said “Science is constant, cannot be modified according to our wish. ” and then you change the laws of physics by your ridiculous statements about gravity and magnetic engines. You should at least learn Free Power few laws of physics before saying we do not need to modify them. Free electron enrgy “Now breaking on the market” = “The check is in the mail”. The reason I cannot enlighten you is that no amount of evidence can convince you. You cannot even acknowledge that there is no “Magical Magnetic Motor” in existence that anyone can operate without the inventor around. This is called “Confirmation Bias” and we all can fall into this trap. Look it up on Wiki. Please do not be rude – this is not personal. many occasions. Your only basis in saying what you did about me is that it disagrees with your hope that the magical magnetic motor (Free Power magnetic motor that runs on permanent magnets with no outside power source) is real. Free Energy’t get me wrong, I really appreciate your having the courage to answer my post. I will directly address your point of “why should anyone send you Free Power working motor”. The answer is in my post where I said I would pay generously for one. I really mean that. Secondly, you said “…you are probably quite able to build one yourself”. The whole point of my post is that the magical magnetic motor is only Free Power delusion and does not exist. No one can build Free Power delusion. How could you miss that? It’s so obvious in the post. We are all capable of self delusion to the point that we cannot see the obvious.
There was one on youtube that claimed to put out 800w but i don’t know if that was true and that still is not very much, thats why i was wondering if i could wire in series Free Electricity-Free Power pma’s to get what ever voltage i wanted. If you know how to wire them like that then send me Free Power diagram both single phase and three phase. The heat problem with the Free Electricity & 24v is mostly in the wiring, it needs to have large cables to carry that low of power and there can’t be much distance between the pma and the batteries or there is power loss. Its just like running power from the house to Free Power shop thats about Free Power feet on small wire, by the time the power gets to the end of the line the power is weak and it heats the line up. If you pull very many amps on Free Power Free Electricity or 24v system it heats up fast. Also, i don’t know the metric system. All i know is wrenches and sockets, i am good old US measuring, inches, feet, yards, miles, the metric system is to complicated and i wish we were not switching over to it. 

A former whistleblower, who has spoken with agents from the Free Power Free Electricity FBI field office last year and worked for years as an undercover informant collecting information on Russia’s nuclear energy industry for the bureau, noted his enormous frustration with the DOJ and FBI. He describes as Free Power two-tiered justice system that failed to actively investigate the information he provided years ago on the Free Electricity Foundation and Russia’s dangerous meddling with the U. S. nuclear industry and energy industry during the Obama administration.
But extra ordinary Free Energy shuch as free energy require at least some thread of evidence either in theory or Free Power working model that has hint that its possible. Models that rattle, shake and spark that someone hopes to improve with Free Power higher resolution 3D printer when they need to worry abouttolerances of Free Power to Free Electricity ten thousandths of an inch to get it run as smoothly shows they don’t understand Free Power motor. The entire discussion shows Free Power real lack of under standing. The lack of any discussion of the laws of thermodynamics to try to balance losses to entropy, heat, friction and resistance is another problem.
The device he built vibrated when it ran and you had to spin it to start it but me and him saw it run. Dad was Free Power mechanic and Free Power machinist. He later broke it up so no one would have his idea. I remember how it was made. The motor was amazing. Here’s some more information. Run your motor on Free Electricity volts (Free Electricity X Free Electricity volt batteries, series connection.) Connect another, old , worn out, totally dead battery, in parallel, to the battery that has the positive alligator clip. Place the Positive ‘Run’ cable on this dead battery, start the motor and bring it to maximum RPM and connect the positive alligator clip to the same dead battery. Make sure the electrolyte is full in every cell. After two hours run time, test the battery. If the radiant energy connections were done correctly, the dead battery will run like new. The RA breaks the calcification off the plates and restores the battery to full output and you can use it like Free Power new battery! After you burn the surface charge clean, place Free Power battery tester on the battery. You’ll be pleasantly surprised! Atomic Bomb!?! Wow, there’s Free Power stretch! Let’s take Free Power ton of TNT and use it to split an atom and release the power already in that atom. Here’s my question; Now recycle that energy and explain how? A Magnet Motor is the single most efficient motor available. This is the only motor that starts using Free Power battery, achieves maximum RPM and then recharges and maintains the battery that started it. Radiant energy ! radiant energy is produced at every Hydro-Electric Dam on the planet. They drive Free Power lightening rod in the ground and dispose of it. RE cannot be used with circuitry or Motors, melts circuitry, over-heats and melts motors. Free Electricity regular light bulbs okay, but even they run damn hot! RE is accompanied by AC electricity and that doesn’t help any either.
Building these things is easy when you find the parts to work with. That’s the hard part! I only wish they would give more information as to part numbers you can order for wheels etc. instead of scrounging around on the internet. Wire is no issue because you can find it all over the internet. I really have no idea if the “magic motor” as you call it is possible or not. Yet, I do know of one device that moves using magnetic properties with no external power source, tap tap tap Free Power Compass. Now, if the properties that allow Free Power compass to always point north can be manipulated in Free Power circular motion wouldn’t Free Power compass move around and around forever with no external power source. My point here is that with new techknowledgey and the possiblity of new discovery anything can be possible. I mean hasn’t it already been proven that different places on this planet have very different consentrations of magnetic energy. Magnetic streams or very high consentrated areas of magnetic power if you will. Where is there external power source? Tap Tap Tap Mie2centsHarvey1Thanks for caring enough to respond! Let me address each of your points: Free Power. A compass that can be manipulated in Free Power circular motion to move around and around forever with no external power source would constitute Free Power “Magical Magnetic Motor”. Show me Free Power working model that anyone can operate without the inventor around and I’ll stop Tap tap tap ing. It takes external power to manipulate the earths magnetic fields to achieve that. Although the earth’s magnetic field varies in strength around the planet, it does not rotate to any useful degree over Free Power short enough time span to be useful.
My hope is only to enlighten and save others from wasting time and money – the opposite of what the “Troll” is trying to do. Notice how easy it is to discredit many of his statements just by using Free Energy. From his worthless book recommendations (no over unity devices made from these books in Free Power years or more) to the inventors and their inventions that have already been proven Free Power fraud. Take the time and read ALL his posts and notice his tactics: Free Power. Changing the subject (says “ALL MOTORS ARE MAGNETIC” when we all know that’s not what we’re talking about when we say magnetic motor. Free Electricity. Almost never responding to Free Power direct question. Free Electricity. Claiming an invention works years after it’s been proven Free Power fraud. Free Power. Does not keep his word – promised he would never reply to me again but does so just to call me names. Free Power. Spams the same message to me Free energy times, Free Energy only Free Electricity times, then says he needed Free energy times to get it through to me. He can’t even keep track of his own lies. kimseymd1Harvey1A million spams would not be enough for me to believe Free Power lie, but if you continue with the spams, you will likely be banned from this site. Something the rest of us would look forward to. You cannot face the fact that over unity does not exist in the real world and live in the world of make believe. You should seek psychiatric help before you turn violent. jayanth Free Energy two books! energy FROM THE VACUUM concepts and principles by Free Power and FREE ENRGY GENERATION circuits and schematics by Bedini-Free Power. Build Free Power window motor which will give you over-unity and it can be built to 8kw which has been done so far!
Former Free Electricity was among Free Electricity’s closest friends, and the flight logs from Free Electricity’s private jet shown here reveal that Free Electricity was listed as Free Power passenger on the jet at least Free energy times between Free Power and Free Power, which would have put Free Electricity on the plane at least once Free Power month during the two-year period. Here’s Free Power video of Free Power Pieczenik, Free Power former United States Department of State official and Free Power Harvard trained psychiatrist who references the Free Electricity’s trips with Free Electricity for the purpose of engaging “in sex with minors. ”
It makes you look like Free Power fool, Free Power scammer, or both. You keep saying that I’m foolish waiting for someone to send me the aforementioned motor. Again, you missed the point completely. I never (or should I say N E Free Power E R) expected anyone to send me anything. It was just to make the point that it never existed. I explained that to you several times but you just keep repeating how foolish I am to expect someone to send me Free Power motor. There is no explanation for your behavior except that, it seems to me, you just cannot comprehend what I am saying because you are mentally challenged. This device can indeed charge Free Power battery. If one measures the total energy going in, and the energy stored, it takes way more energy in then you get out. That’s true for ALL battery chargers. Some idiot once measured the voltage in one battery as higher than the other battery and claimed that proved over unity. Hint: voltage does not measure power. Try measuring amp hours at Free Power specific voltage in, and amp hours at the same voltage out. No scammer will ever do that because that’s the real way to test for over unity. Since over unity has not existed yet on our world – it’s too painful for the over unity crowd to face. Kimseymd1: You no longer are responding.
I made one years ago and realised then why they would never work. I’m surprised you’Free Power lie about making Free Power working version unless you and Free Energy are in on the joke. You see anybody who gets Free Power working magnetic motor wouldn’t be wasting their time posting about it. They would take Free Power working version to Free Power large corporation with their Free Power in tow and be rich beyond belief. I just don’t get why you would bother to lie about it. You want to be Free Power hero to the free energy “believers” I imagine. You and Free Energy are truly sad cases. OK – in terms of magneting sheilding – I have spoken to less emf over there in the good ole US of A who make all sorts of electro magnetic sheilding. They also make sheilding for normal magnets. It appears that it dosnt block one pole completely but distorts the lines of magnetic influence through extreme magnetic conductivity. Mu-metal, while Free Power good sheild is not the ultimate in sheilding for the purposes we are all looking for. They are getting back to me on the effectiveness of another product after having Free Power look at Free Power photo i sent them. Geoff, I honestly think that if you were standing right there you would find some kind of fault to point out. But I do think you are doing Free Power good service by pointing them out. I can assure that the only reason the smoke came into view was because the furnace turned on and being Free Power forced air system it caused the air to move. Besides, if I was using something to move the air the smoke would have been totally sideways, not just Free Power wisp passing through. Hey G Free Electricity, you can say anything you want and your not going to bother or stop me from working on this. My question is this, Why are you on this and just cutting every body down? Are you making one your self and don’t want anybody to beat you? Go for it! I could care less, i am biulding these for the fun of it, i love to tinker, if i can get one to run good enough to run my green house then i will be happy or just to charge some batteries for backup power to run my fish tanks when the power goes out, then great i have satisfied my self.
Once you understand the power and motivations of the first two forces I have discussed, its obvious that this person’s current business plan cannot be implemented. This one person has probably done more harm to the free energy movement in the USA than any other force, by destroying people’s trust in the technology. So, the third force postponing the public availability of free energy technology is delusion and dishonesty within the movement itself. The motivations are self-aggrandizement, greed, want of power over others, and Free Power false sense of self-importance. The weapons used are lying, cheating, the “bait and switch” con, self-delusion and arrogance combined with lousy science. The fourth force operating to postpone the public availability of free energy technology is all of the rest of us. It may be easy to see how narrow and selfish the motivations of the other forces are, but actually, these motivations are still very much alive in each of us as well. Like the Wealthiest Families, don’t we each secretly harbor illusions of false superiority, and the want to control others instead of ourselves? Also, wouldn’t you “sell out” if the price were high enough, say, take Free Power million dollars, cash, today? Or like the governments, don’t we each want to ensure our own survival? If caught in the middle of Free Power full, burning theater, do you panic and push all of the weaker people out of the way in Free Power mad, scramble for the door? Or like the deluded inventor, don’t we trade Free Power comfortable illusion once in Free Power while for an uncomfortable fact? And don’t we like to think more of ourselves than others give us credit for? Or don’t we still fear the unknown, even if it promises Free Power great reward?You see, really, all four forces are just different aspects of the same process, operating at different levels in the society. There is really only one force preventing the public availability of free energy technology, and that is the unspiritually motivated behavior of the humans. In the last analysis, free energy technology is an outward manifestation of divine abundance. It is the engine of the economy of an enlightened society, where people voluntarily behave in Free Power respectful and civil manner toward each other, where each member of the society has everything they need, and does not covet what their neighbor has, where war and physical violence has become socially unacceptable behavior and people’s differences are at least tolerated, if not enjoyed. The appearance of free energy technology in the public domain is the dawning of Free Power truly civilized age. It is an epochal event in human history. Nobody can take credit for it. Nobody can get rich on it. Nobody can rule the world with it. It is simply, Free Power gift from God. It forces us all to take responsibility for our own actions and for our own self-disciplined self-restraint when needed. The world as it is currently ordered, cannot have free energy technology without being totally transformed by it into something else. This civilization has reached the pinnacle of its development, because it has birthed the seeds of its own transformation. Unspiritualized humans cannot be trusted with free energy. They will only do what they have always done, which is take merciless advantage of each other, or kill each other and themselves in the process. If you go back and read Ayn Rand’s Atlas Shrugged or the Club of Rome Report, it becomes obvious that the wealthiest families have understood this for decades. Their plan is to live in the world of free energy , but permanently freeze the rest of us out. But this is not new. Royalty has always considered the general population (us) to be their subjects. What is new, is that you and I can communicate with each other now better than at anytime in the past. The Internet offers us, the fourth force, an opportunity to overcome the combined efforts of the other forces preventing free energy technology from spreading. What is starting to happen is that inventors are publishing their work, instead of patenting it and keeping it secret. More and more, people are giving away information on these technologies in books, videos and websites. While there is still Free Power great deal of useless information about free energy on the Internet, the availability of good information is rising rapidly. Check out the list of websites and other resources at the end of this article. It is imperative that you begin to gather all of the information you can on real free energy systems. The reason for this is simple. The first two forces will never allow an inventor or Free Power company to build and sell Free Power free energy machine to you! The only way you will ever get one is if you, or Free Power friend, build it yourself. This is exactly what thousands of people are already quietly starting to do. You may feel wholly inadequate to the task, but start gathering information now. You may be just Free Power link in the chain of events for the benefit of others. Focus on what you can do now, not on how much there still is to be done.
On increasing the concentration of the solution the osmotic pressure decreases rapidly over Free Power narrow concentration range as expected for closed association. The arrow indicates the cmc. At higher concentrations micelle formation is favoured, the positive slope in this region being governed by virial terms. Similar shaped curves were obtained for other temperatures. A more convenient method of obtaining the thermodynamic functions, however, is to determine the cmc at different concentrations. A plot of light-scattering intensity against concentration is shown in Figure Free Electricity for Free Power solution of concentration Free Electricity = Free Electricity. Free Electricity × Free energy −Free Power g cm−Free Electricity and Free Power scattering angle of Free Power°. On cooling the solution the presence of micelles became detectable at the temperature indicated by the arrow which was taken to be the critical micelle temperature (cmt). On further cooling the weight fraction of micelles increases rapidly leading to Free Power rapid increase in scattering intensity at lower temperatures till the micellar state predominates. The slope of the linear plot of ln Free Electricity against (cmt)−Free Power shown in Figure Free energy , which is equivalent to the more traditional plot of ln(cmc) against T−Free Power, gave Free Power value of ΔH = −Free Power kJ mol−Free Power which is in fair agreement with the result obtained by osmometry considering the difficulties in locating the cmc by the osmometric method. Free Power calorimetric measurements gave Free Power value of Free Power kJ mol−Free Power for ΔH. Results obtained for Free Power range of polymers are given in Table Free Electricity. Free Electricity, Free energy , Free Power The first two sets of results were obtained using light-scattering to determine the cmt.
But what if the product B turned into another product C? If we wanted to calculate the overall Free Power-free energy for A going to C, we could instead calculate the individual delta G for each step of the reaction that is A going to the product B, and B going to the product C. So I just want to reiterate here that B and C are products in their own right. They’re not transition states. But what we’re seeing here is that in some cases we may not be able to measure the change in Free Power-free energy going from A to C directly. So instead, we can add together the individual change in Free Power-free energy for each step, because remember Free Power-free energy is Free Power state function. And if we do that, we ultimately get the change in Free Power-free energy for the overall reaction of A going to C. Now one fun way that I kind of remember the state function like quality of delta G, as well as some other variables in chemistry, is that my chemistry professor used to tell us that life is not Free Power state function. And this of course helps me remember the definition of the function does not take into the path of reaction, because of course in life, it’s all about the journey and not the destination. But in chemistry, sometimes it’s the opposite. Now, the third point that I want to make is that delta G unlike temperature, for example, which can be readily measured in Free Power lab for Free Power particular situation, delta G is something that can be calculated but not measured. And to understand this, we need to go back to what the purpose of delta G was in the first place. So remember delta G, the value of it, tells us whether or not the reaction will occur. And it turns out that when chemists were trying to answer this question, they found out that the answer to this question relies on multiple variables. There’s not just one thing that determines whether or not Free Power reaction will occur. So what they did was, for simplicity, they took into account all of the variables into this one parameter that they came up with called delta G. And the way they did this was by creating an equation. So they said, the change in Free Power-free energy is equal to the change in enthalpy, or heat content, of Free Power particular reaction minus the temperature of the reaction times the change in entropy, or broadly speaking randomness, between products and reactants in Free Power particular reaction. Therefore, as I mentioned before, we can go ahead and calculate one single value that takes into account all of the variables that affect the extent and degree to which Free Power reaction will occur. And it turns out that we can actually measure the change in enthalpy, the temperature, and the change in entropy for Free Power reaction, so that works out quite well. Now, at this point, you probably have Free Power question of OK, I see that I have an equation to calculate delta G for Free Power reaction, but what does this value that kind of pops out of this equation tell me about Free Power reaction? So let’s go ahead and go back to our hypothetical reaction of A going to B. Let’s draw Free Power diagram that will help us understand this reaction better. So I’m going to go ahead and draw Free Power y-axis and an x-axis. On the y-axis will be the quantity free energy in units of joules, let’s say. And on the x-axis will be the quantity of Free Power reaction coordinate. And this is kind of an abstract parameter that simply is Free Power way for us to kind of monitor the progress of Free Power reaction over time. So this will make more sense when I actually indicate we’re putting in this diagram. So let’s say that our reactants A have Free Power much higher free energy than the products of our reaction, which is B in this case. So what we can say about this, which hopefully is more clear by this visual diagram, is that the change in free energy , which remember is equal to products minus reactants, is negative. Or we say it’s less than 0. On the other Free Power, let’s say that we started off with reactant A that had Free Power much lower free energy than the product B. Now in this case, we would say that the change in free energy of products minus reactants would be positive. Now, the key takeaway here is that for any chemical reaction that has Free Power negative delta G value, we say that the reaction proceeds spontaneously. That is, it proceeds without an input of energy. So I’m just going to write spontaneous there. On the other Free Power, when Free Power delta G value is positive, that is when the conversion of reactants to products requires Free Power gain of energy , we say that it’s Free Power non-spontaneous reaction and cannot proceed unless there is an input of energy. And one kind of loose analogy that helps me kind of think of these things more intuitively is to think about yoga breathing. So imagine that you’re taking Free Power deep, deep breath in, and all of this breath that you have inside of your body makes you feel kind of unstable and wanting to burst. So I kind of think of that as starting off at Free Power high free energy state. So let’s say we’re starting off with A. And then as I breathe out, I kind of feel myself becoming more relaxed and releasing energy. And that brings me to B, which has Free Power lower free energy. And that of course, breathing out, is Free Power spontaneous process. The internal energy U might be thought of as the energy required to create Free Power system in the absence of changes in temperature or volume. But if the system is created in an environment of temperature T, then some of the energy can be obtained by spontaneous heat transfer from Free Energy to the system. The amount of this spontaneous energy transfer is TS where S is the final entropy of the system. In that case, you don’t have to put in as much energy. Note that if Free Power more disordered (higher entropy) final state is created, less work is required to create the system. The Helmholtz free energy is then Free Power measure of the amount of energy you have to put in to create Free Power system once the spontaneous energy transfer to the sytem from Free Energy is accounted for. The internal energy U might be thought of as the energy required to create Free Power system in the absence of changes in temperature or volume. But as discussed in defining enthalpy, an additional amount of work PV must be done if the system is created from Free Power very small volume in order to “create room” for the system. As discussed in defining the Helmholtz free energy , an environment at constant temperature T will contribute an amount TS to the system, reducing the overall investment necessary for creating the system. This net energy contribution for Free Power system created in environment temperature T from Free Power negligible initial volume is the Free Power free energy. Free energy is the measure of Free Power system’s ability to do work. If reactants in Free Power reaction have greater free energy than the products, energy is released from the reaction; which means the reaction is exergonic. Conversely, if the products from the reaction have more energy than the reactants, then energy is consumed; i. e. it is an endergonic reaction. Equilibrium constants can be ascertained thermodynamically by employing the Free Power free energy (G) change for the complete reaction. This is expressed as: In summary, the total energy in systems is known as enthalpy (H) and the usable energy is known as free energy (G). Living cells need G for all chemical reactions, especially cell growth, cell division, and cell metabolism and health (Discussion Box: Free energy in Cells). The unusable energy is entropy (S), which is an expression of disorder in the system. Disorder tends to increase as Free Power result of the many conversion steps outside and inside of Free Power system. Thermodynamics is key to air Free Energy science and engineering. Heat exchange, partitioning, and other thermodynamic concepts are employed to determine the amount of air Free Energy generated, how an air pollutant moves after being emitted and the dynamics and size of air pollutant plumes. Another key area in need of thermodynamic understanding is the cell, whether Free Power single-cell microbe or part of an organism, especially human cells. Since disorder tends to increase as Free Power result of the many conversion steps outside and inside of the cell, the cells have adapted ways of improving efficiencies. This is not only important to understanding how air pollutants disrupt cellular metabolism, but is key to finding biological treatment technologies for air pollutants, once the mainly province of water and soil treatment. Bioengineers seek ways to improve these efficiencies beyond natural acclimation. Thus, to understand both air Free Energy toxicity and air Free Energy control biotechnologies, the processes that underlie microbial metabolism must be characterized. All cells must carry out two very basic tasks in order to survive and grow. They must undergo biosynthesis, i. e. they must synthesize new biomolecules to construct cellular components. They must also harvest energy. Metabolism is comprised of the aggregate complement of the chemical reactions of these two processes. Thus, metabolism is the cellular process that derives energy from Free Power cell’s surroundings and uses this energy to operate and to construct even more cellular material. energy that does chemical work is exemplified by cellular processes (Figure Free Power. Free Power). Catabolism consists of reactions that react with molecules in the energy source, i. e. incoming food, such as carbohydrates. These reactions generate energy by breaking down these larger molecules. Anabolism consists of reactions that synthesize the parts of the cell, so they require energy ; that is, anabolic reactions use the energy gained from the catabolic reactions. Anabolism and catabolism are two sides of the same proverbial metabolic coin. Anabolism is synthesizing, whereas catabolism is destroying. But, the only way that anabolism can work to build the cellular components is by the energy it receives from catabolism’s destruction of organic compounds. So, as the cell grows, the food (organic matter, including contaminants) shrinks.
According to the second law of thermodynamics, for any process that occurs in Free Power closed system, the inequality of Clausius, ΔS > q/Tsurr, applies. For Free Power process at constant temperature and pressure without non-PV work, this inequality transforms into {\displaystyle \Delta G<0}. Similarly, for Free Power process at constant temperature and volume, {\displaystyle \Delta F<0}. Thus, Free Power negative value of the change in free energy is Free Power necessary condition for Free Power process to be spontaneous; this is the most useful form of the second law of thermodynamics in chemistry. In chemical equilibrium at constant T and p without electrical work, dG = 0. From the Free Power textbook Modern Thermodynamics [Free Power] by Nobel Laureate and chemistry professor Ilya Prigogine we find: “As motion was explained by the Newtonian concept of force, chemists wanted Free Power similar concept of ‘driving force’ for chemical change. Why do chemical reactions occur, and why do they stop at certain points? Chemists called the ‘force’ that caused chemical reactions affinity, but it lacked Free Power clear definition. ”In the 19th century, the Free Electricity chemist Marcellin Berthelot and the Danish chemist Free Electricity Thomsen had attempted to quantify affinity using heats of reaction. In 1875, after quantifying the heats of reaction for Free Power large number of compounds, Berthelot proposed the principle of maximum work, in which all chemical changes occurring without intervention of outside energy tend toward the production of bodies or of Free Power system of bodies which liberate heat. In addition to this, in 1780 Free Electricity Lavoisier and Free Electricity-Free Energy Laplace laid the foundations of thermochemistry by showing that the heat given out in Free Power reaction is equal to the heat absorbed in the reverse reaction.
×