But what if the product B turned into another product C? If we wanted to calculate the overall Free Power-free energy for A going to C, we could instead calculate the individual delta G for each step of the reaction that is A going to the product B, and B going to the product C. So I just want to reiterate here that B and C are products in their own right. They’re not transition states. But what we’re seeing here is that in some cases we may not be able to measure the change in Free Power-free energy going from A to C directly. So instead, we can add together the individual change in Free Power-free energy for each step, because remember Free Power-free energy is Free Power state function. And if we do that, we ultimately get the change in Free Power-free energy for the overall reaction of A going to C. Now one fun way that I kind of remember the state function like quality of delta G, as well as some other variables in chemistry, is that my chemistry professor used to tell us that life is not Free Power state function. And this of course helps me remember the definition of the function does not take into the path of reaction, because of course in life, it’s all about the journey and not the destination. But in chemistry, sometimes it’s the opposite. Now, the third point that I want to make is that delta G unlike temperature, for example, which can be readily measured in Free Power lab for Free Power particular situation, delta G is something that can be calculated but not measured. And to understand this, we need to go back to what the purpose of delta G was in the first place. So remember delta G, the value of it, tells us whether or not the reaction will occur. And it turns out that when chemists were trying to answer this question, they found out that the answer to this question relies on multiple variables. There’s not just one thing that determines whether or not Free Power reaction will occur. So what they did was, for simplicity, they took into account all of the variables into this one parameter that they came up with called delta G. And the way they did this was by creating an equation. So they said, the change in Free Power-free energy is equal to the change in enthalpy, or heat content, of Free Power particular reaction minus the temperature of the reaction times the change in entropy, or broadly speaking randomness, between products and reactants in Free Power particular reaction. Therefore, as I mentioned before, we can go ahead and calculate one single value that takes into account all of the variables that affect the extent and degree to which Free Power reaction will occur. And it turns out that we can actually measure the change in enthalpy, the temperature, and the change in entropy for Free Power reaction, so that works out quite well. Now, at this point, you probably have Free Power question of OK, I see that I have an equation to calculate delta G for Free Power reaction, but what does this value that kind of pops out of this equation tell me about Free Power reaction? So let’s go ahead and go back to our hypothetical reaction of A going to B. Let’s draw Free Power diagram that will help us understand this reaction better. So I’m going to go ahead and draw Free Power y-axis and an x-axis. On the y-axis will be the quantity free energy in units of joules, let’s say. And on the x-axis will be the quantity of Free Power reaction coordinate. And this is kind of an abstract parameter that simply is Free Power way for us to kind of monitor the progress of Free Power reaction over time. So this will make more sense when I actually indicate we’re putting in this diagram. So let’s say that our reactants A have Free Power much higher free energy than the products of our reaction, which is B in this case. So what we can say about this, which hopefully is more clear by this visual diagram, is that the change in free energy , which remember is equal to products minus reactants, is negative. Or we say it’s less than 0. On the other Free Power, let’s say that we started off with reactant A that had Free Power much lower free energy than the product B. Now in this case, we would say that the change in free energy of products minus reactants would be positive. Now, the key takeaway here is that for any chemical reaction that has Free Power negative delta G value, we say that the reaction proceeds spontaneously. That is, it proceeds without an input of energy. So I’m just going to write spontaneous there. On the other Free Power, when Free Power delta G value is positive, that is when the conversion of reactants to products requires Free Power gain of energy , we say that it’s Free Power non-spontaneous reaction and cannot proceed unless there is an input of energy. And one kind of loose analogy that helps me kind of think of these things more intuitively is to think about yoga breathing. So imagine that you’re taking Free Power deep, deep breath in, and all of this breath that you have inside of your body makes you feel kind of unstable and wanting to burst. So I kind of think of that as starting off at Free Power high free energy state. So let’s say we’re starting off with A. And then as I breathe out, I kind of feel myself becoming more relaxed and releasing energy. And that brings me to B, which has Free Power lower free energy. And that of course, breathing out, is Free Power spontaneous process. The internal energy U might be thought of as the energy required to create Free Power system in the absence of changes in temperature or volume. But if the system is created in an environment of temperature T, then some of the energy can be obtained by spontaneous heat transfer from Free Energy to the system. The amount of this spontaneous energy transfer is TS where S is the final entropy of the system. In that case, you don’t have to put in as much energy. Note that if Free Power more disordered (higher entropy) final state is created, less work is required to create the system. The Helmholtz free energy is then Free Power measure of the amount of energy you have to put in to create Free Power system once the spontaneous energy transfer to the sytem from Free Energy is accounted for. The internal energy U might be thought of as the energy required to create Free Power system in the absence of changes in temperature or volume. But as discussed in defining enthalpy, an additional amount of work PV must be done if the system is created from Free Power very small volume in order to “create room” for the system. As discussed in defining the Helmholtz free energy , an environment at constant temperature T will contribute an amount TS to the system, reducing the overall investment necessary for creating the system. This net energy contribution for Free Power system created in environment temperature T from Free Power negligible initial volume is the Free Power free energy. Free energy is the measure of Free Power system’s ability to do work. If reactants in Free Power reaction have greater free energy than the products, energy is released from the reaction; which means the reaction is exergonic. Conversely, if the products from the reaction have more energy than the reactants, then energy is consumed; i. e. it is an endergonic reaction. Equilibrium constants can be ascertained thermodynamically by employing the Free Power free energy (G) change for the complete reaction. This is expressed as: In summary, the total energy in systems is known as enthalpy (H) and the usable energy is known as free energy (G). Living cells need G for all chemical reactions, especially cell growth, cell division, and cell metabolism and health (Discussion Box: Free energy in Cells). The unusable energy is entropy (S), which is an expression of disorder in the system. Disorder tends to increase as Free Power result of the many conversion steps outside and inside of Free Power system. Thermodynamics is key to air Free Energy science and engineering. Heat exchange, partitioning, and other thermodynamic concepts are employed to determine the amount of air Free Energy generated, how an air pollutant moves after being emitted and the dynamics and size of air pollutant plumes. Another key area in need of thermodynamic understanding is the cell, whether Free Power single-cell microbe or part of an organism, especially human cells. Since disorder tends to increase as Free Power result of the many conversion steps outside and inside of the cell, the cells have adapted ways of improving efficiencies. This is not only important to understanding how air pollutants disrupt cellular metabolism, but is key to finding biological treatment technologies for air pollutants, once the mainly province of water and soil treatment. Bioengineers seek ways to improve these efficiencies beyond natural acclimation. Thus, to understand both air Free Energy toxicity and air Free Energy control biotechnologies, the processes that underlie microbial metabolism must be characterized. All cells must carry out two very basic tasks in order to survive and grow. They must undergo biosynthesis, i. e. they must synthesize new biomolecules to construct cellular components. They must also harvest energy. Metabolism is comprised of the aggregate complement of the chemical reactions of these two processes. Thus, metabolism is the cellular process that derives energy from Free Power cell’s surroundings and uses this energy to operate and to construct even more cellular material. energy that does chemical work is exemplified by cellular processes (Figure Free Power. Free Power). Catabolism consists of reactions that react with molecules in the energy source, i. e. incoming food, such as carbohydrates. These reactions generate energy by breaking down these larger molecules. Anabolism consists of reactions that synthesize the parts of the cell, so they require energy ; that is, anabolic reactions use the energy gained from the catabolic reactions. Anabolism and catabolism are two sides of the same proverbial metabolic coin. Anabolism is synthesizing, whereas catabolism is destroying. But, the only way that anabolism can work to build the cellular components is by the energy it receives from catabolism’s destruction of organic compounds. So, as the cell grows, the food (organic matter, including contaminants) shrinks.

Reality is never going to be accepted by tat section of the community. Thanks for writing all about the phase conjugation stuff. I know there are hundreds of devices out there, and I would just buy one, as I live in an apartment now, and if the power goes out here for any reason, we would have to watch TV by candle light. lol. I was going to buy Free Power small generator from the store, but I cant even run it outside on the balcony. So I was going to order Free Power magnetic motor, but nobody sell them, you can only buy plans, and build it yourself. And I figured, because it dont work, and I remembered, that I designed something like that in the 1950s, that I never build, and as I can see nobody designed, or build one like that, I dont know how it will work, but it have Free Power much better chance of working, than everything I see out there, so I m planning to build one when I move out of the city. But if you or any one wants to look at it, or build it, I could e-mail the plans to you. 

Free Energy Wedger, Free Power retired police detective with over Free energy years of service in the investigation of child abuse was Free Power witness to the ITNJ and explains who is involved in these rings, and how it operates continually without being taken down. It’s because, almost every time, the ‘higher ups’ are involved and completely shut down any type of significant inquiry.
In the 18th and 19th centuries, the theory of heat, i. e. , that heat is Free Power form of energy having relation to vibratory motion, was beginning to supplant both the caloric theory, i. e. , that heat is Free Power fluid, and the four element theory, in which heat was the lightest of the four elements. In Free Power similar manner, during these years, heat was beginning to be distinguished into different classification categories, such as “free heat”, “combined heat”, “radiant heat”, specific heat, heat capacity, “absolute heat”, “latent caloric”, “free” or “perceptible” caloric (calorique sensible), among others.
It is merely Free Power magnetic coupling that operates through Free Power right angle. It is not Free Power free energy device or Free Power magnetic motor. Not relevant to this forum. Am I overlooking something. Would this not be perpetual motion because the unit is using already magents which have stored energy. Thus the unit is using energy that is stored in the magents making the unit using energy this disolving perpetual as the magents will degrade over time. It may be hundreds of years for some magents but they will degrade anyway. The magents would be acting as batteries even if they do turn. I spoke with PBS/NOVA. They would be interested in doing an in-depth documentary on the Yildiz device. I contacted Mr. Felber, Mr. Yildiz’s EPO rep, and he is going to talk to him about getting the necessary releases. Presently Mr. Yildiz’s only Intellectual Property Rights protection is Free Power Patent Application (in U. S. , Free Power Provisional Patent). But he is going to discuss it with him. Mr. Free Electricity, then we do agree, as I agree based on your definition. That is why the term self-sustaining, which gets to the root of the problem…Free Power practical solution to alternative energy , whether using magnets, Free Energy-Fe-nano-Phosphate batteries or something new that comes down the pike. Free Energy, NASA’s idea of putting tethered cables into space to turn the earth into Free Power large generator even makes sense. My internal mental debate is based on Free Power device I experimented on. Taking an inverter and putting an alternator on the shaft of the inverter, I charged an off-line battery while using up the one battery.
I then alternated the charge/depletion process until everything ran down. The device with the alternator in place ran much longer than with it removed, which is the opposite of what one would expect. My imagination currently is trying to determine how long the “system” would run if tuned and using the new Free Energy-Fe-nano-phosphate batteries rather than the lead acid batteries I used previously. And could the discharged batteries be charged up quicker than the recharged battery is depleted, making for Free Power useful, practical motor? Free Energy are claiming to have invented perpetual motion MACHINES. That is my gripe. No one has ever demonstrated Free Power working version of such Free Power beast or explained how it could work(in terms that make sense – and as arrogant as this may sound, use of Zero Point energy or harnessing gravity waves or similar makes as much sense as saying it uses powdered unicorn horns as the secret ingredient).
Now, let’s go ahead and define the change in free energy for this particular reaction. Now as is implied by this delta sign, we’re measuring Free Power change. So in this case, we’re measuring the free energy of our product, which is B minus the free energy of our reactant, which in this case is A. But this general product minus reactant change is relevant for any chemical reaction that you will come across. Now at this point, right at the outset, I want to make three main points about this value delta G. And if you understand these points, you pretty much are on your way to understanding and being able to apply this quantity delta G to any reaction that you see. Now, the first point I want to make has to do with units. So delta G is usually reported in units of– and these brackets just indicate that I’m telling you what the units are for this value– the units are generally reported as joules per mole of reactant. So in the case of our example above, the delta G value for A turning into B would be reported as some number of joules per mole of A. And this intuitively makes sense, because we’re talking about an energy change, and joules is the unit that’s usually used for energy. And we generally refer to quantities in chemistry of reactants or products in terms of molar quantities. Now, the second point I want to make is that the change in Free Power-free energy is only concerned with the products and the reactants of Free Power reaction not the pathway of the reaction itself. It’s what chemists call Free Power “state function. ” And this is Free Power really important property of delta G that we take advantage of, especially in biochemistry, because it allows us to add the delta G value from multiple reactions that are taking place in an overall metabolic pathway. So to return to our example above, we had A turning into Free Power product B.
But I will send you the plan for it whenever you are ready. What everyone seems to miss is that magnetic fields are not directional. Thus when two magnets are brought together in Free Power magnetic motor the force of propulsion is the same (measured as torque on the shaft) whether the motor is turned clockwise or anti-clockwise. Thus if the effective force is the same in both directions what causes it to start to turn and keep turning? (Hint – nothing!) Free Energy, I know this works because mine works but i do need better shielding and you told me to use mumetal. What is this and where do you get it from? Also i would like to just say something here just so people don’t get to excited. In order to run Free Power generator say Free Power Free Electricity-10k it would take Free Power magnetic motor with rotors 8ft in diameter with the strongest magnets you can find and several rotors all on the same shaft just to turn that one generator. Thats alot of money in magnets. One example of the power it takes is this.
I believe that is what is happening in regards to Free Power motor that needs no external power to operate. As proof of that, I have supplied an incentive for anyone to send me Free Power motor in return for Free Power generous reward. The very reason I put the “Focus” paragraph in was in the hope that it would show the deluded following that the motor does not exist anywhere. Nothing short of Free Power real working model would prove it’s not Free Power delusion. Stay focused on that and you will see the truth of what I am saying. Harvey1A magical magnetic motor? Motors have been greatly enhanced with the advent of super magnets in just ten years. Smaller and more powerful to say the least. In my mind over unity is simply Free Power better way of using electricity to create Free Power better generator.
What may finally soothe the anger of Free Power D. Free Energy and other whistleblowers is that their time seems to have finally come to be heard, and perhaps even have their findings acted upon, as today’s hearing seems to be striking Free Power different tone to the ears of those who have in-depth knowledge of the crimes that have been alleged. This is certainly how rep. Free Power Free Electricity, Free Power member of the Free Energy Oversight and Government Reform Committee, sees it:
No real world proof that the known laws of physics have been proven wrong. No real world proof of anything. Try this – just for Free Power few minutes make yourself believe that the whole over unity concept is Free Power scam. Free Electricity for Free Power few minutes while reading all my posts without forming responses in your mind. Then after you’ve read the posts, see if you can honestly start believing in over unity again. My goal is to try and get people to stop wasting time going down dead ends, not to stifle creativity. I think the key to the permanent magnet motor is Free Power material that surrounds the magnet on Free Power Free Energy (being one of Free Power number of them) forcing the flux to come out of one side therefore Free Power magnet on the outside can focus the same polarity flux to repel the magnet on the Free Energy and turn it. The material Free Power file is made of seems to be the key since flux doesn’t seem to pass through it or another material that stops the flux from passing through it Free Energy seem to use the term perpetual motor which will never be until you have Free Power permanent magnet motor, or generator with frictionless air bearings. Then they will work as long as the magnets don’t ware out. It took Free energy weeks to get from searching for perpetual motors or generators to permanent magnet motors which is closer to reality. There is Free Power lot of fraud in perpetual motion machines but not so much in permanent magnet motors and generators. kimseymd1 ” but not so much in permanent magnet motors and generators. ” What are you talking about? Free Electricity from nuts? Fake videos? Free Electricity of Free Power friend has one? How about facing the real fact that no one has ever had Free Power real working Magical Magnetic Motor that anyone can operate. Come on, acknowledge what I saFree Energy No excuses. No delusions. No “It’s about to be released” No stupid fake videos with the inventor hovering around like Free Power mother hawk and Free Power rotating magnet under the table making it look like the motor is working. No using semantics to avoid the subject. There are NO REAL WORKING EXAMPLES EVER.
We can make the following conclusions about when processes will have Free Power negative \Delta \text G_\text{system}ΔGsystem​: \begin{aligned} \Delta \text G &= \Delta \text H – \text{T}\Delta \text S \ \ &= Free energy. 01 \dfrac{\text{kJ}}{\text{mol-rxn}}-(Free energy \, \cancel{\text K})(0. 022\, \dfrac{\text{kJ}}{\text{mol-rxn}\cdot \cancel{\text K})} \ \ &= Free energy. 01\, \dfrac{\text{kJ}}{\text{mol-rxn}}-Free energy. Free Power\, \dfrac{\text{kJ}}{\text{mol-rxn}}\ \ &= -0. Free Electricity \, \dfrac{\text{kJ}}{\text{mol-rxn}}\end{aligned}ΔG​=ΔH−TΔS=Free energy. 01mol-rxnkJ​−(293K)(0. 022mol-rxn⋅K)kJ​=Free energy. 01mol-rxnkJ​−Free energy. 45mol-rxnkJ​=−0. 44mol-rxnkJ​​ Being able to calculate \Delta \text GΔG can be enormously useful when we are trying to design experiments in lab! We will often want to know which direction Free Power reaction will proceed at Free Power particular temperature, especially if we are trying to make Free Power particular product. Chances are we would strongly prefer the reaction to proceed in Free Power particular direction (the direction that makes our product!), but it’s hard to argue with Free Power positive \Delta \text GΔG! Our bodies are constantly active. Whether we’re sleeping or whether we’re awake, our body’s carrying out many chemical reactions to sustain life. Now, the question I want to explore in this video is, what allows these chemical reactions to proceed in the first place. You see we have this big idea that the breakdown of nutrients into sugars and fats, into carbon dioxide and water, releases energy to fuel the production of ATP, which is the energy currency in our body. Many textbooks go one step further to say that this process and other energy -releasing processes– that is to say, chemical reactions that release energy. Textbooks say that these types of reactions have something called Free Power negative delta G value, or Free Power negative Free Power-free energy. In this video, we’re going to talk about what the change in Free Power free energy , or delta G as it’s most commonly known is, and what the sign of this numerical value tells us about the reaction. Now, in order to understand delta G, we need to be talking about Free Power specific chemical reaction, because delta G is quantity that’s defined for Free Power given reaction or Free Power sum of reactions. So for the purposes of simplicity, let’s say that we have some hypothetical reaction where A is turning into Free Power product B. Now, whether or not this reaction proceeds as written is something that we can determine by calculating the delta G for this specific reaction. So just to phrase this again, the delta G, or change in Free Power-free energy , reaction tells us very simply whether or not Free Power reaction will occur.
Free Power, Free Power paper in the journal Physical Review A, Puthoff titled “Source of vacuum electromagnetic zero-point energy , ” (source) Puthoff describes how nature provides us with two alternatives for the origin of electromagnetic zero-point energy. One of them is generation by the quantum fluctuation motion of charged particles that constitute matter. His research shows that particle motion generates the zero-point energy spectrum, in the form of Free Power self-regenerating cosmological feedback cycle.
Air Free Energy biotechnology takes advantage of these two metabolic functions, depending on the microbial biodegradability of various organic substrates. The microbes in Free Power biofilter, for example, use the organic compounds as their exclusive source of energy (catabolism) and their sole source of carbon (anabolism). These life processes degrade the pollutants (Figure Free Power. Free energy). Microbes, e. g. algae, bacteria, and fungi, are essentially miniature and efficient chemical factories that mediate reactions at various rates (kinetics) until they reach equilibrium. These “simple” organisms (and the cells within complex organisms alike) need to transfer energy from one site to another to power their machinery needed to stay alive and reproduce. Microbes play Free Power large role in degrading pollutants, whether in natural attenuation, where the available microbial populations adapt to the hazardous wastes as an energy source, or in engineered systems that do the same in Free Power more highly concentrated substrate (Table Free Power. Free Electricity). Some of the biotechnological manipulation of microbes is aimed at enhancing their energy use, or targeting the catabolic reactions toward specific groups of food, i. e. organic compounds. Thus, free energy dictates metabolic processes and biological treatment benefits by selecting specific metabolic pathways to degrade compounds. This occurs in Free Power step-wise progression after the cell comes into contact with the compound. The initial compound, i. e. the parent, is converted into intermediate molecules by the chemical reactions and energy exchanges shown in Figures Free Power. Free Power and Free Power. Free Power. These intermediate compounds, as well as the ultimate end products can serve as precursor metabolites. The reactions along the pathway depend on these precursors, electron carriers, the chemical energy , adenosine triphosphate (ATP), and organic catalysts (enzymes). The reactant and product concentrations and environmental conditions, especially pH of the substrate, affect the observed ΔG∗ values. If Free Power reaction’s ΔG∗ is Free Power negative value, the free energy is released and the reaction will occur spontaneously, and the reaction is exergonic. If Free Power reaction’s ΔG∗ is positive, the reaction will not occur spontaneously. However, the reverse reaction will take place, and the reaction is endergonic. Time and energy are limiting factors that determine whether Free Power microbe can efficiently mediate Free Power chemical reaction, so catalytic processes are usually needed. Since an enzyme is Free Power biological catalyst, these compounds (proteins) speed up the chemical reactions of degradation without themselves being used up.
But thats what im thinkin about now lol Free Energy Making Free Power metal magnetic does not put energy into for later release as energy. That is one of the classic “magnetic motor” myths. Agree there will be some heat (energy) transfer due to eddy current losses but that is marginal and not recoverable. I takes Free Power split second to magnetise material. Free Energy it. Stroke an iron nail with Free Power magnet and it becomes magnetic quite quickly. Magnetising something merely aligns existing small atomic sized magnetic fields.

Thanks Free Electricity, you told me some things i needed to know and it just confirmed my thinking on the way we are building these motors. My motor runs but not the way it needs to to be of any real use. I am going to abandon my motor and go with Free Power whole differant design. The mags are going to be Free Power differant shape set in the rotor differant so that shielding can be used in Free Power much more efficient way. Sorry for getting Free Power little snippy with you, i just do not like being told what i can and cannot do, maybe it was the fact that when i was Free Power kidd i always got told no. It’s something i still have Free Power problem with even at my age. After i get more info on the shielding i will probably be gone for Free Power while, while i design and build my new motor. I am Free Power machanic for Free Power concrete pumping company and we are going into spring now here in Utah which means we start to get busy. So between work, house, car&truck upkeep, yard & garden and family, there is not alot of time for tinkering but i will do my best. Free Power, please get back to us on the shielding. Free Power As I stated magnets lose strength for specific reasons and mechanical knocks etc is what causes the cheap ones to do exactly that as you describe. I used to race model cars and had to replace the ceramic magnets often due to the extreme knocks they used to get. My previous post about magnets losing their power was specifically about neodymium types – these have Free Power very low rate of “aging” and as my research revealed they are stated as losing Free Power strength in the first Free energy years. But extreme mishandling will shorten their life – normal use won’t. Fridge magnets and the like have very weak abilities to hold there magnetic properties – I certainly agree. But don’t believe these magnets are releasing energy that could be harnessed.

But what if the product B turned into another product C? If we wanted to calculate the overall Free Power-free energy for A going to C, we could instead calculate the individual delta G for each step of the reaction that is A going to the product B, and B going to the product C. So I just want to reiterate here that B and C are products in their own right. They’re not transition states. But what we’re seeing here is that in some cases we may not be able to measure the change in Free Power-free energy going from A to C directly. So instead, we can add together the individual change in Free Power-free energy for each step, because remember Free Power-free energy is Free Power state function. And if we do that, we ultimately get the change in Free Power-free energy for the overall reaction of A going to C. Now one fun way that I kind of remember the state function like quality of delta G, as well as some other variables in chemistry, is that my chemistry professor used to tell us that life is not Free Power state function. And this of course helps me remember the definition of the function does not take into the path of reaction, because of course in life, it’s all about the journey and not the destination. But in chemistry, sometimes it’s the opposite. Now, the third point that I want to make is that delta G unlike temperature, for example, which can be readily measured in Free Power lab for Free Power particular situation, delta G is something that can be calculated but not measured. And to understand this, we need to go back to what the purpose of delta G was in the first place. So remember delta G, the value of it, tells us whether or not the reaction will occur. And it turns out that when chemists were trying to answer this question, they found out that the answer to this question relies on multiple variables. There’s not just one thing that determines whether or not Free Power reaction will occur. So what they did was, for simplicity, they took into account all of the variables into this one parameter that they came up with called delta G. And the way they did this was by creating an equation. So they said, the change in Free Power-free energy is equal to the change in enthalpy, or heat content, of Free Power particular reaction minus the temperature of the reaction times the change in entropy, or broadly speaking randomness, between products and reactants in Free Power particular reaction. Therefore, as I mentioned before, we can go ahead and calculate one single value that takes into account all of the variables that affect the extent and degree to which Free Power reaction will occur. And it turns out that we can actually measure the change in enthalpy, the temperature, and the change in entropy for Free Power reaction, so that works out quite well. Now, at this point, you probably have Free Power question of OK, I see that I have an equation to calculate delta G for Free Power reaction, but what does this value that kind of pops out of this equation tell me about Free Power reaction? So let’s go ahead and go back to our hypothetical reaction of A going to B. Let’s draw Free Power diagram that will help us understand this reaction better. So I’m going to go ahead and draw Free Power y-axis and an x-axis. On the y-axis will be the quantity free energy in units of joules, let’s say. And on the x-axis will be the quantity of Free Power reaction coordinate. And this is kind of an abstract parameter that simply is Free Power way for us to kind of monitor the progress of Free Power reaction over time. So this will make more sense when I actually indicate we’re putting in this diagram. So let’s say that our reactants A have Free Power much higher free energy than the products of our reaction, which is B in this case. So what we can say about this, which hopefully is more clear by this visual diagram, is that the change in free energy , which remember is equal to products minus reactants, is negative. Or we say it’s less than 0. On the other Free Power, let’s say that we started off with reactant A that had Free Power much lower free energy than the product B. Now in this case, we would say that the change in free energy of products minus reactants would be positive. Now, the key takeaway here is that for any chemical reaction that has Free Power negative delta G value, we say that the reaction proceeds spontaneously. That is, it proceeds without an input of energy. So I’m just going to write spontaneous there. On the other Free Power, when Free Power delta G value is positive, that is when the conversion of reactants to products requires Free Power gain of energy , we say that it’s Free Power non-spontaneous reaction and cannot proceed unless there is an input of energy. And one kind of loose analogy that helps me kind of think of these things more intuitively is to think about yoga breathing. So imagine that you’re taking Free Power deep, deep breath in, and all of this breath that you have inside of your body makes you feel kind of unstable and wanting to burst. So I kind of think of that as starting off at Free Power high free energy state. So let’s say we’re starting off with A. And then as I breathe out, I kind of feel myself becoming more relaxed and releasing energy. And that brings me to B, which has Free Power lower free energy. And that of course, breathing out, is Free Power spontaneous process. The internal energy U might be thought of as the energy required to create Free Power system in the absence of changes in temperature or volume. But if the system is created in an environment of temperature T, then some of the energy can be obtained by spontaneous heat transfer from Free Energy to the system. The amount of this spontaneous energy transfer is TS where S is the final entropy of the system. In that case, you don’t have to put in as much energy. Note that if Free Power more disordered (higher entropy) final state is created, less work is required to create the system. The Helmholtz free energy is then Free Power measure of the amount of energy you have to put in to create Free Power system once the spontaneous energy transfer to the sytem from Free Energy is accounted for. The internal energy U might be thought of as the energy required to create Free Power system in the absence of changes in temperature or volume. But as discussed in defining enthalpy, an additional amount of work PV must be done if the system is created from Free Power very small volume in order to “create room” for the system. As discussed in defining the Helmholtz free energy , an environment at constant temperature T will contribute an amount TS to the system, reducing the overall investment necessary for creating the system. This net energy contribution for Free Power system created in environment temperature T from Free Power negligible initial volume is the Free Power free energy. Free energy is the measure of Free Power system’s ability to do work. If reactants in Free Power reaction have greater free energy than the products, energy is released from the reaction; which means the reaction is exergonic. Conversely, if the products from the reaction have more energy than the reactants, then energy is consumed; i. e. it is an endergonic reaction. Equilibrium constants can be ascertained thermodynamically by employing the Free Power free energy (G) change for the complete reaction. This is expressed as: In summary, the total energy in systems is known as enthalpy (H) and the usable energy is known as free energy (G). Living cells need G for all chemical reactions, especially cell growth, cell division, and cell metabolism and health (Discussion Box: Free energy in Cells). The unusable energy is entropy (S), which is an expression of disorder in the system. Disorder tends to increase as Free Power result of the many conversion steps outside and inside of Free Power system. Thermodynamics is key to air Free Energy science and engineering. Heat exchange, partitioning, and other thermodynamic concepts are employed to determine the amount of air Free Energy generated, how an air pollutant moves after being emitted and the dynamics and size of air pollutant plumes. Another key area in need of thermodynamic understanding is the cell, whether Free Power single-cell microbe or part of an organism, especially human cells. Since disorder tends to increase as Free Power result of the many conversion steps outside and inside of the cell, the cells have adapted ways of improving efficiencies. This is not only important to understanding how air pollutants disrupt cellular metabolism, but is key to finding biological treatment technologies for air pollutants, once the mainly province of water and soil treatment. Bioengineers seek ways to improve these efficiencies beyond natural acclimation. Thus, to understand both air Free Energy toxicity and air Free Energy control biotechnologies, the processes that underlie microbial metabolism must be characterized. All cells must carry out two very basic tasks in order to survive and grow. They must undergo biosynthesis, i. e. they must synthesize new biomolecules to construct cellular components. They must also harvest energy. Metabolism is comprised of the aggregate complement of the chemical reactions of these two processes. Thus, metabolism is the cellular process that derives energy from Free Power cell’s surroundings and uses this energy to operate and to construct even more cellular material. energy that does chemical work is exemplified by cellular processes (Figure Free Power. Free Power). Catabolism consists of reactions that react with molecules in the energy source, i. e. incoming food, such as carbohydrates. These reactions generate energy by breaking down these larger molecules. Anabolism consists of reactions that synthesize the parts of the cell, so they require energy ; that is, anabolic reactions use the energy gained from the catabolic reactions. Anabolism and catabolism are two sides of the same proverbial metabolic coin. Anabolism is synthesizing, whereas catabolism is destroying. But, the only way that anabolism can work to build the cellular components is by the energy it receives from catabolism’s destruction of organic compounds. So, as the cell grows, the food (organic matter, including contaminants) shrinks.

To understand why this is the case, it’s useful to bring up the concept of chemical equilibrium. As Free Power refresher on chemical equilibrium, let’s imagine that we start Free Power reversible reaction with pure reactants (no product present at all). At first, the forward reaction will proceed rapidly, as there are lots of reactants that can be converted into products. The reverse reaction, in contrast, will not take place at all, as there are no products to turn back into reactants. As product accumulates, however, the reverse reaction will begin to happen more and more often. This process will continue until the reaction system reaches Free Power balance point, called chemical equilibrium, at which the forward and reverse reactions take place at the same rate. At this point, both reactions continue to occur, but the overall concentrations of products and reactants no longer change. Each reaction has its own unique, characteristic ratio of products to reactants at equilibrium. When Free Power reaction system is at equilibrium, it is in its lowest-energy state possible (has the least possible free energy).
These functions have Free Power minimum in chemical equilibrium, as long as certain variables (T, and Free Power or p) are held constant. In addition, they also have theoretical importance in deriving Free Power relations. Work other than p dV may be added, e. g. , for electrochemical cells, or f dx work in elastic materials and in muscle contraction. Other forms of work which must sometimes be considered are stress-strain, magnetic, as in adiabatic demagnetization used in the approach to absolute zero, and work due to electric polarization. These are described by tensors.
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