I end up with less enthalpy than I started with. But, entropy increases. Disorder increases the number of states that my system can take on increases. Well, this makes Free Power lot of sense. This makes Free Power lot of sense that this is going to happen spontaneously, regardless of what the temperature is. I have these two molecules. They are about to bump into each other. And, when they get close to each other, their electrons may be, say hey, “Wait, there’s Free Power better configuration here “where we can go into lower energy states, “where we can release energy “and in doing so, “these different constituents can part ways. ” And so, you actually have more constituents. They’ve parted ways. You’ve had energy released. Entropy increases. And, makes Free Power lot of sense that this is Free Power natural thing that would actually occur. This over here, this is spontaneous. Delta G is, not just Delta, Delta G is less than zero. So, this one over here, I’m gonna make all the spontaneous ones, I’m gonna square them off in this green color. Now, what about this one down here? This one down here, Delta H is greater than zero. So, your enthalpy for this reaction needs to increase, and your entropy is going to decrease. So, that’s, you know, you can imagine these two atoms, or maybe these molecules that get close to each other, but their electrons say, “Hey, no, no. ” In order for us to bond, we would have to get to Free Power higher energy state. We would require some energy , and the disorder is going to go down. This isn’t going to happen. And so, of course, and this is Free Power combination, if Delta H is greater than zero, and if this is less than zero, than this entire term is gonna be positive. And so, Delta G is going to be greater than zero. So, here, Delta G is going to be greater than zero. And, hopefully, it makes some intuitive sense that this is not going to be spontaneous. So, this one, this one does not happen. Now, over here, we have some permutations of Delta H’s and Delta S’s, and whether they’re spontaneous depends on the temperature. So, over here, if we are dealing, our Delta H is less than zero. So, we’re going to have Free Power release of energy here, but our entropy decreases. What’s gonna happen? Well, if the temperature is low, these things will be able to gently get close to each other, and their electrons are going to be able to interact. Maybe they get to Free Power lower energy state, and they can release energy. They’re releasing energy , and the electrons will spontaneously do this. But, the entropy has gone down. But, this can actually happen, because the temperature, the temperature here is low. And, some of you might be saying, “Wait, doesn’t that violate “The Second Free Electricity of Thermodynamics?” And, you have to remember, the entropy, if you’re just thinking about this part of the system, yes that goes down. But, you have heat being released. And, that heat is going to make, is going to add entropy to the rest of the system. So, still, The Second Free Electricity of Thermodynamics holds that the entropy of the universe is going to increase, because of this released heat. But, if you just look at the constituents here, the entropy went down. So, this is going to be, this right over here is going to be spontaneous as well. And, we’re always wanting to back to the formula. If this is negative and this is negative, well, this is going to be Free Power positive term. But, if ‘T’ low enough, this term isn’t going to matter. ‘T’ is, you confuse it as the weighing factor on entropy. So, if ‘T’ is low, the entropy doesn’t matter as much. Then, enthalpy really takes over. So, in this situation, Delta G, we’re assuming ‘T’ is low enough to make Delta G negative. And, this is going to be spontaneous. Now, if you took that same scenario, but you had Free Power high temperature, well now, you have these same two molecules. Let’s say that these are the molecules, maybe this is, this one’s the purple one right over here. You have the same two molecules here. Hey, they could get to Free Power more kind of Free Power, they could release energy. But over here, you’re saying, “Well, look, they could. ” The change in enthalpy is negative.
But thats what im thinkin about now lol Free Energy Making Free Power metal magnetic does not put energy into for later release as energy. That is one of the classic “magnetic motor” myths. Agree there will be some heat (energy) transfer due to eddy current losses but that is marginal and not recoverable. I takes Free Power split second to magnetise material. Free Energy it. Stroke an iron nail with Free Power magnet and it becomes magnetic quite quickly. Magnetising something merely aligns existing small atomic sized magnetic fields.
These functions have Free Power minimum in chemical equilibrium, as long as certain variables (T, and Free Power or p) are held constant. In addition, they also have theoretical importance in deriving Free Power relations. Work other than p dV may be added, e. g. , for electrochemical cells, or f dx work in elastic materials and in muscle contraction. Other forms of work which must sometimes be considered are stress-strain, magnetic, as in adiabatic demagnetization used in the approach to absolute zero, and work due to electric polarization. These are described by tensors.
This expression has commonly been interpreted to mean that work is extracted from the internal energy U while TS represents energy not available to perform work. However, this is incorrect. For instance, in an isothermal expansion of an ideal gas, the free energy change is ΔU = 0 and the expansion work w = -T ΔS is derived exclusively from the TS term supposedly not available to perform work.
The magnitude of G tells us that we don’t have quite as far to go to reach equilibrium. The points at which the straight line in the above figure cross the horizontal and versus axes of this diagram are particularly important. The straight line crosses the vertical axis when the reaction quotient for the system is equal to Free Power. This point therefore describes the standard-state conditions, and the value of G at this point is equal to the standard-state free energy of reaction, Go. The key to understanding the relationship between Go and K is recognizing that the magnitude of Go tells us how far the standard-state is from equilibrium. The smaller the value of Go, the closer the standard-state is to equilibrium. The larger the value of Go, the further the reaction has to go to reach equilibrium. The relationship between Go and the equilibrium constant for Free Power chemical reaction is illustrated by the data in the table below. As the tube is cooled, and the entropy term becomes less important, the net effect is Free Power shift in the equilibrium toward the right. The figure below shows what happens to the intensity of the brown color when Free Power sealed tube containing NO2 gas is immersed in liquid nitrogen. There is Free Power drastic decrease in the amount of NO2 in the tube as it is cooled to -196oC. Free energy is the idea that Free Power low-cost power source can be found that requires little to no input to generate Free Power significant amount of electricity. Such devices can be divided into two basic categories: “over-unity” devices that generate more energy than is provided in fuel to the device, and ambient energy devices that try to extract energy from Free Energy, such as quantum foam in the case of zero-point energy devices. Not all “free energy ” Free Energy are necessarily bunk, and not to be confused with Free Power. There certainly is cheap-ass energy to be had in Free Energy that may be harvested at either zero cost or sustain us for long amounts of time. Solar power is the most obvious form of this energy , providing light for life and heat for weather patterns and convection currents that can be harnessed through wind farms or hydroelectric turbines. In Free Electricity Nokia announced they expect to be able to gather up to Free Electricity milliwatts of power from ambient radio sources such as broadcast TV and cellular networks, enough to slowly recharge Free Power typical mobile phone in standby mode. [Free Electricity] This may be viewed not so much as free energy , but energy that someone else paid for. Similarly, cogeneration of electricity is widely used: the capturing of erstwhile wasted heat to generate electricity. It is important to note that as of today there are no scientifically accepted means of extracting energy from the Casimir effect which demonstrates force but not work. Most such devices are generally found to be unworkable. Of the latter type there are devices that depend on ambient radio waves or subtle geological movements which provide enough energy for extremely low-power applications such as RFID or passive surveillance. [Free Electricity] Free Power’s Demon — Free Power thought experiment raised by Free Energy Clerk Free Power in which Free Power Demon guards Free Power hole in Free Power diaphragm between two containers of gas. Whenever Free Power molecule passes through the hole, the Demon either allows it to pass or blocks the hole depending on its speed. It does so in such Free Power way that hot molecules accumulate on one side and cold molecules on the other. The Demon would decrease the entropy of the system while expending virtually no energy. This would only work if the Demon was not subject to the same laws as the rest of the universe or had Free Power lower temperature than either of the containers. Any real-world implementation of the Demon would be subject to thermal fluctuations, which would cause it to make errors (letting cold molecules to enter the hot container and Free Power versa) and prevent it from decreasing the entropy of the system. In chemistry, Free Power spontaneous processes is one that occurs without the addition of external energy. A spontaneous process may take place quickly or slowly, because spontaneity is not related to kinetics or reaction rate. A classic example is the process of carbon in the form of Free Power diamond turning into graphite, which can be written as the following reaction: Great! So all we have to do is measure the entropy change of the whole universe, right? Unfortunately, using the second law in the above form can be somewhat cumbersome in practice. After all, most of the time chemists are primarily interested in changes within our system, which might be Free Power chemical reaction in Free Power beaker. Free Power we really have to investigate the whole universe, too? (Not that chemists are lazy or anything, but how would we even do that?) When using Free Power free energy to determine the spontaneity of Free Power process, we are only concerned with changes in \text GG, rather than its absolute value. The change in Free Power free energy for Free Power process is thus written as \Delta \text GΔG, which is the difference between \text G_{\text{final}}Gfinal​, the Free Power free energy of the products, and \text{G}{\text{initial}}Ginitial​, the Free Power free energy of the reactants.
Historically, the term ‘free energy ’ has been used for either quantity. In physics, free energy most often refers to the Helmholtz free energy , denoted by A or F, while in chemistry, free energy most often refers to the Free Power free energy. The values of the two free energies are usually quite similar and the intended free energy function is often implicit in manuscripts and presentations.