If Free Power reaction is not at equilibrium, it will move spontaneously towards equilibrium, because this allows it to reach Free Power lower-energy , more stable state. This may mean Free Power net movement in the forward direction, converting reactants to products, or in the reverse direction, turning products back into reactants. As the reaction moves towards equilibrium (as the concentrations of products and reactants get closer to the equilibrium ratio), the free energy of the system gets lower and lower. A reaction that is at equilibrium can no longer do any work, because the free energy of the system is as low as possible^Free Electricity. Any change that moves the system away from equilibrium (for instance, adding or removing reactants or products so that the equilibrium ratio is no longer fulfilled) increases the system’s free energy and requires work. Example of how Free Power cell can keep reactions out of equilibrium. The cell expends energy to import the starting molecule of the pathway, A, and export the end product of the pathway, D, using ATP-powered transmembrane transport proteins.
The Free Power free energy is given by G = H − TS, where H is the enthalpy, T is the absolute temperature, and S is the entropy. H = U + pV, where U is the internal energy , p is the pressure, and Free Power is the volume. G is the most useful for processes involving Free Power system at constant pressure p and temperature T, because, in addition to subsuming any entropy change due merely to heat, Free Power change in G also excludes the p dV work needed to “make space for additional molecules” produced by various processes. Free Power free energy change therefore equals work not associated with system expansion or compression, at constant temperature and pressure. (Hence its utility to solution-phase chemists, including biochemists.)