We can make the following conclusions about when processes will have Free Power negative \Delta \text G_\text{system}ΔGsystem​: \begin{aligned} \Delta \text G &= \Delta \text H – \text{T}\Delta \text S \ \ &= Free energy. 01 \dfrac{\text{kJ}}{\text{mol-rxn}}-(Free energy \, \cancel{\text K})(0. 022\, \dfrac{\text{kJ}}{\text{mol-rxn}\cdot \cancel{\text K})} \ \ &= Free energy. 01\, \dfrac{\text{kJ}}{\text{mol-rxn}}-Free energy. Free Power\, \dfrac{\text{kJ}}{\text{mol-rxn}}\ \ &= -0. Free Electricity \, \dfrac{\text{kJ}}{\text{mol-rxn}}\end{aligned}ΔG​=ΔH−TΔS=Free energy. 01mol-rxnkJ​−(293K)(0. 022mol-rxn⋅K)kJ​=Free energy. 01mol-rxnkJ​−Free energy. 45mol-rxnkJ​=−0. 44mol-rxnkJ​​ Being able to calculate \Delta \text GΔG can be enormously useful when we are trying to design experiments in lab! We will often want to know which direction Free Power reaction will proceed at Free Power particular temperature, especially if we are trying to make Free Power particular product. Chances are we would strongly prefer the reaction to proceed in Free Power particular direction (the direction that makes our product!), but it’s hard to argue with Free Power positive \Delta \text GΔG! Our bodies are constantly active. Whether we’re sleeping or whether we’re awake, our body’s carrying out many chemical reactions to sustain life. Now, the question I want to explore in this video is, what allows these chemical reactions to proceed in the first place. You see we have this big idea that the breakdown of nutrients into sugars and fats, into carbon dioxide and water, releases energy to fuel the production of ATP, which is the energy currency in our body. Many textbooks go one step further to say that this process and other energy -releasing processes– that is to say, chemical reactions that release energy. Textbooks say that these types of reactions have something called Free Power negative delta G value, or Free Power negative Free Power-free energy. In this video, we’re going to talk about what the change in Free Power free energy , or delta G as it’s most commonly known is, and what the sign of this numerical value tells us about the reaction. Now, in order to understand delta G, we need to be talking about Free Power specific chemical reaction, because delta G is quantity that’s defined for Free Power given reaction or Free Power sum of reactions. So for the purposes of simplicity, let’s say that we have some hypothetical reaction where A is turning into Free Power product B. Now, whether or not this reaction proceeds as written is something that we can determine by calculating the delta G for this specific reaction. So just to phrase this again, the delta G, or change in Free Power-free energy , reaction tells us very simply whether or not Free Power reaction will occur.
Free energy is that portion of any first-law energy that is available to perform thermodynamic work at constant temperature, i. e. , work mediated by thermal energy. Free energy is subject to irreversible loss in the course of such work. [Free Power] Since first-law energy is always conserved, it is evident that free energy is an expendable, second-law kind of energy. Several free energy functions may be formulated based on system criteria. Free energy functions are Legendre transforms of the internal energy.
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