Free Power’s law is overridden by Pauli’s law, where in general there must be gaps in heat transfer spectra and broken sýmmetry between the absorption and emission spectra within the same medium and between disparate media, and Malus’s law, where anisotropic media like polarizers selectively interact with radiation.

Free energy is that portion of any first-law energy that is available to perform thermodynamic work at constant temperature, i. e. , work mediated by thermal energy. Free energy is subject to irreversible loss in the course of such work. [Free Power] Since first-law energy is always conserved, it is evident that free energy is an expendable, second-law kind of energy. Several free energy functions may be formulated based on system criteria. Free energy functions are Legendre transforms of the internal energy.