But, they’re buzzing past each other so fast that they’re not gonna have Free Power chance. Their electrons aren’t gonna have Free Power chance to actually interact in the right way for the reaction to actually go on. And so, this is Free Power situation where it won’t be spontaneous, because they’re just gonna buzz past each other. They’re not gonna have Free Power chance to interact properly. And so, you can imagine if ‘T’ is high, if ‘T’ is high, this term’s going to matter Free Power lot. And, so the fact that entropy is negative is gonna make this whole thing positive. And, this is gonna be more positive than this is going to be negative. So, this is Free Power situation where our Delta G is greater than zero. So, once again, not spontaneous. And, everything I’m doing is just to get an intuition for why this formula for Free Power Free energy makes sense. And, remember, this is true under constant pressure and temperature. But, those are reasonable assumptions if we’re dealing with, you know, things in Free Power test tube, or if we’re dealing with Free Power lot of biological systems. Now, let’s go over here. So, our enthalpy, our change in enthalpy is positive. And, our entropy would increase if these react, but our temperature is low. So, if these reacted, maybe they would bust apart and do something, they would do something like this. But, they’re not going to do that, because when these things bump into each other, they’re like, “Hey, you know all of our electrons are nice. “There are nice little stable configurations here. “I don’t see any reason to react. ” Even though, if we did react, we were able to increase the entropy. Hey, no reason to react here. And, if you look at these different variables, if this is positive, even if this is positive, if ‘T’ is low, this isn’t going to be able to overwhelm that. And so, you have Free Power Delta G that is greater than zero, not spontaneous. If you took the same scenario, and you said, “Okay, let’s up the temperature here. “Let’s up the average kinetic energy. ” None of these things are going to be able to slam into each other. And, even though, even though the electrons would essentially require some energy to get, to really form these bonds, this can happen because you have all of this disorder being created. You have these more states. And, it’s less likely to go the other way, because, well, what are the odds of these things just getting together in the exact right configuration to get back into these, this lower number of molecules. And, once again, you look at these variables here. Even if Delta H is greater than zero, even if this is positive, if Delta S is greater than zero and ‘T’ is high, this thing is going to become, especially with the negative sign here, this is going to overwhelm the enthalpy, and the change in enthalpy, and make the whole expression negative. So, over here, Delta G is going to be less than zero. And, this is going to be spontaneous. Hopefully, this gives you some intuition for the formula for Free Power Free energy. And, once again, you have to caveat it. It’s under, it assumes constant pressure and temperature. But, it is useful for thinking about whether Free Power reaction is spontaneous. And, as you look at biological or chemical systems, you’ll see that Delta G’s for the reactions. And so, you’ll say, “Free Electricity, it’s Free Power negative Delta G? “That’s going to be Free Power spontaneous reaction. “It’s Free Power zero Delta G. “That’s gonna be an equilibrium. ”
Free energy is that portion of any first-law energy that is available to perform thermodynamic work at constant temperature, i. e. , work mediated by thermal energy. Free energy is subject to irreversible loss in the course of such work. [Free Power] Since first-law energy is always conserved, it is evident that free energy is an expendable, second-law kind of energy. Several free energy functions may be formulated based on system criteria. Free energy functions are Legendre transforms of the internal energy.